Methyl 2-<(Z)-bis-1,4-(tert-butyldimethylsiloxy)-2-buten-2-yl>-5-methylbenzoate

Base Information

Chemical Name:Methyl 2-<(Z)-bis-1,4-(tert-butyldimethylsiloxy)-2-buten-2-yl>-5-methylbenzoate
CAS No.:125131-09-1
Molecular Formula:C₂₅H₄₄O₄Si₂
Molecular Weight:464.793
Hs Code.:

Synonyms:Methyl 2-<(Z)-bis-1,4-(tert-butyldimethylsiloxy)-2-buten-2-yl>-5-methylbenzoate

Suppliers and Price of Methyl 2-<(Z)-bis-1,4-(tert-butyldimethylsiloxy)-2-buten-2-yl>-5-methylbenzoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Methyl 2-<(Z)-bis-1,4-(tert-butyldimethylsiloxy)-2-buten-2-yl>-5-methylbenzoate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Methyl 2-<(Z)-bis-1,4-(tert-butyldimethylsiloxy)-2-buten-2-yl>-5-methylbenzoate

There total 2 articles about Methyl 2-<(Z)-bis-1,4-(tert-butyldimethylsiloxy)-2-buten-2-yl>-5-methylbenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

: 103440-52-4
methyl 2-iodo-5-methylbenzoate

: 125131-08-0,130767-18-9
(Z)-1,4-Bis-(tert-butyldimethylsiloxy)-2-tri-n-butylstannyl-2-butene

: 125131-09-1
Methyl 2-<(Z)-bis-1,4-(tert-butyldimethylsiloxy)-2-buten-2-yl>-5-methylbenzoate

Guidance literature:: bis-triphenylphosphine-palladium(II) chloride; lithium chloride; zinc(II) chloride; In 1,4-dioxane; for 48h; Heating;
DOI:10.1016/S0040-4020(01)85578-2

Reference yield:

: 52548-14-8
2-iodoyl-5-methylbenzoic acid

: 125131-09-1
Methyl 2-<(Z)-bis-1,4-(tert-butyldimethylsiloxy)-2-buten-2-yl>-5-methylbenzoate

Guidance literature:: Multi-step reaction with 2 steps

1: 88 percent / AcCl / 14 h / Heating

2: 43 percent / Pd(PPh₃)2Cl₂/ ZnCl₂/ LiCl / dioxane / 48 h / Heating

With acetyl chloride; bis-triphenylphosphine-palladium(II) chloride; lithium chloride; zinc(II) chloride; In 1,4-dioxane;
DOI:10.1016/S0040-4020(01)85578-2

Reference yield:

: 125131-09-1
Methyl 2-<(Z)-bis-1,4-(tert-butyldimethylsiloxy)-2-buten-2-yl>-5-methylbenzoate

: 130767-21-4
(4Z)-7-Methyl-4-(2-p-toluenesulphonylethyliden-1-yl)-isochroman-1-one

Guidance literature:: Multi-step reaction with 3 steps

1: 83 percent / 2M HCl / tetrahydrofuran / 1.75 h / Ambient temperature

2: 81 percent / NBS, PPh₃ / CH₂Cl₂ / 4.5 h / Ambient temperature

3: 61 percent / dimethylformamide / 5 h / Ambient temperature

With hydrogenchloride; N-Bromosuccinimide; triphenylphosphine; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4020(01)85578-2