(E)-5-[4'-(2-biphenyl-4-yl-vinyl)-biphenyl-4-ylmethoxymethyl]-[2,2']bipyridine

Base Information

• Chemical Name: (E)-5-[4'-(2-biphenyl-4-yl-vinyl)-biphenyl-4-ylmethoxymethyl]-[2,2']bipyridine
• CAS No.: 875634-86-9
• Molecular Formula: C₃₈H₃₀N₂O
• Molecular Weight: 530.669
• Mol file: 875634-86-9.mol

Synonyms:(E)-5-[4'-(2-biphenyl-4-yl-vinyl)-biphenyl-4-ylmethoxymethyl]-[2,2']bipyridine

Chemical Property of (E)-5-[4'-(2-biphenyl-4-yl-vinyl)-biphenyl-4-ylmethoxymethyl]-[2,2']bipyridine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (E)-5-[4'-(2-biphenyl-4-yl-vinyl)-biphenyl-4-ylmethoxymethyl]-[2,2']bipyridine

There total 1 articles about (E)-5-[4'-(2-biphenyl-4-yl-vinyl)-biphenyl-4-ylmethoxymethyl]-[2,2']bipyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

(Z)-5-[4'-(2-biphenyl-4-yl-vinyl)-biphenyl-4-ylmethoxymethyl]-[2,2']bipyridine (875634-83-6) → (E)-5-[4'-(2-biphenyl-4-yl-vinyl)-biphenyl-4-ylmethoxymethyl]-[2,2']bipyridine (875634-86-9)

Guidance literature:

With 2',4',5',7'-tetraiodofluorescein disodium salt; In tetrahydrofuran; for 21h; UV-irradiation;

DOI:10.1021/ja0561340

Reference yield: 80.0%

(E)-5-[4'-(2-biphenyl-4-yl-vinyl)-biphenyl-4-ylmethoxymethyl]-[2,2']bipyridine (875634-86-9) + ammonium hexafluorophosphate + cis-bis-(2,2′-bipyridine) dichlororuthenium(II) dihydrate → (E)-[5-[4'-(2-biphenyl-4-yl-vinyl)-biphenyl-4-ylmethoxymethyl]-[2,2']bipyridine]-bis(2,2'-bipyridine)ruthenium(II) bis(hexafluorophosphate)

Guidance literature:

With Ag[SbF₆]; In tetrahydrofuran; acetone; byproducts: AgCl; (red light); a soln. of Ru complex and Ag salt in acetone under N2 stirred at 23°C for 72 h, filtered, ligand added, dild. with acetone and THF, refluxed for 28 h, evapd., dissolved in MeCN, aq. NH4PF6 added, stirred at 23°C for 30 min; extd. (CH2Cl2), washed (H2O), evapd. (vac.), dissolved in MeCN, pptd. (Et2O), filtered; elem. anal.;

DOI:10.1021/ja0561340

upstream raw materials:

(Z)-5-[4'-(2-biphenyl-4-yl-vinyl)-biphenyl-4-ylmethoxymethyl]-[2,2']bipyridine