(phenyl)nickel(II)bromide{1,2-bis(diphenylphosphino)ethane}

Base Information

• Chemical Name: (phenyl)nickel(II)bromide{1,2-bis(diphenylphosphino)ethane}
• CAS No.: 115677-85-5
• Molecular Formula: C₃₂H₂₉BrNiP₂
• Molecular Weight: 614.124
• Mol file: 115677-85-5.mol

Synonyms:(phenyl)nickel(II)bromide{1,2-bis(diphenylphosphino)ethane}

Chemical Property of (phenyl)nickel(II)bromide{1,2-bis(diphenylphosphino)ethane}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (phenyl)nickel(II)bromide{1,2-bis(diphenylphosphino)ethane}

There total 3 articles about (phenyl)nickel(II)bromide{1,2-bis(diphenylphosphino)ethane} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

1,2-bis(diphenylphosphino)ethane nickel(II) chloride (14647-23-5) + ethylmagnesium bromide (925-90-6) → (phenyl)nickel(II)bromide{1,2-bis(diphenylphosphino)ethane} (115677-85-5)

Guidance literature:

With (C₆H₅)3P; C₆H₅Br; 1,2-bis(diphenylphosphino)ethane nickel(II) chloride; In diethyl ether; chloroform; Electrochem. Process; Addn. (0°C) of EtMgBr (Et2O) to an Et2O soln. containing NiCl2(dppe) and PPh3, stirring of mixt. (2 h, room temp.).; Sepn. of yellow ppt. by filtn., solubilized with chloroform, addn. of petroleum ether pptd. yellow crystals, drying under vac.;

DOI:10.1021/om00100a019

Reference yield: 57.0%

bromobenzene (108-86-1,52753-63-6) + 1,2-bis(diphenylphosphino)ethane-bis(triphenylphosphine)nickel(0) (54428-80-7) → cis-(bromo)(phenyl)[1,2-bis(diphenylphosphino)ethane]nickel (115677-85-5)

Guidance literature:

In tetrahydrofuran; THF, 40 h;

DOI:10.1021/ja202877q

Reference yield:

bromobenzene (108-86-1,52753-63-6) + diethyl(2,2'-bipyridyl)nickel(II) (15218-76-5) + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → (phenyl)nickel(II)bromide{1,2-bis(diphenylphosphino)ethane} (115677-85-5)

Guidance literature:

In not given;

DOI:10.1021/ja904885w

upstream raw materials:

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

ethylmagnesium bromide

bromobenzene

diethyl(2,2'-bipyridyl)nickel(II)