Technology Process of 1,3,4-Triphenylphosphole 1-oxide
There total 7 articles about 1,3,4-Triphenylphosphole 1-oxide which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
potassium hydroxide;
In
methanol; dichloromethane;
for 5h;
DOI:10.1039/b000692k
- Guidance literature:
-
Multi-step reaction with 4 steps
1: copper(II) stearate / petroleum ether / 384 h / 60 °C
2: 29.3 g / aq. NaHCO3
3: 33 percent / NBS; benzoyl peroxide / CHCl3 / 6 h / Heating
4: 79 percent / KOH / methanol; CH2Cl2 / 5 h
With
potassium hydroxide; N-Bromosuccinimide; copper(II) stearate; sodium hydrogencarbonate; dibenzoyl peroxide;
In
methanol; dichloromethane; chloroform; Petroleum ether;
1: Cyclization / 2: Hydrolysis / 3: Bromination / 4: Dehydrobromination;
DOI:10.1039/b000692k
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: Mg / diethyl ether / 0.67 h
1.2: 76 percent / diethyl ether / 4 h
2.1: 46 percent / KHSO4; phenyl-β-naphthylamine / 0.67 h / 120 °C / 7 - 8 Torr
3.1: copper(II) stearate / petroleum ether / 384 h / 60 °C
4.1: 29.3 g / aq. NaHCO3
5.1: 33 percent / NBS; benzoyl peroxide / CHCl3 / 6 h / Heating
6.1: 79 percent / KOH / methanol; CH2Cl2 / 5 h
With
potassium hydroxide; potassium hydrogensulfate; N-Bromosuccinimide; N-Phenyl-2-naphthylamine; copper(II) stearate; sodium hydrogencarbonate; magnesium; dibenzoyl peroxide;
In
methanol; diethyl ether; dichloromethane; chloroform; Petroleum ether;
1.1: Metallation / 1.2: Grignard reaction / 2.1: Dehydration / 3.1: Cyclization / 4.1: Hydrolysis / 5.1: Bromination / 6.1: Dehydrobromination;
DOI:10.1039/b000692k
