(molybdenum)2(ruthenium)(carbonyl)2(cyclopentadienyl)2(μ3-η6-1,3,5-triphenylhexatrienyl)(μ3-sulfido)*1.5(benzene)

Base Information

Chemical Name:(molybdenum)2(ruthenium)(carbonyl)2(cyclopentadienyl)2(μ3-η6-1,3,5-triphenylhexatrienyl)(μ3-sulfido)*1.5(benzene)
CAS No.:110096-38-3
Molecular Formula:C₆H₆*C₃₆H₂₈Mo₂O₂RuS
Molecular Weight:934.804
Hs Code.:

Synonyms:(molybdenum)2(ruthenium)(carbonyl)2(cyclopentadienyl)2(μ3-η6-1,3,5-triphenylhexatrienyl)(μ3-sulfido)*1.5(benzene)

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Chemical Property of (molybdenum)2(ruthenium)(carbonyl)2(cyclopentadienyl)2(μ3-η6-1,3,5-triphenylhexatrienyl)(μ3-sulfido)*1.5(benzene)

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Technology Process of (molybdenum)2(ruthenium)(carbonyl)2(cyclopentadienyl)2(μ3-η6-1,3,5-triphenylhexatrienyl)(μ3-sulfido)*1.5(benzene)

There total 1 articles about (molybdenum)2(ruthenium)(carbonyl)2(cyclopentadienyl)2(μ3-η6-1,3,5-triphenylhexatrienyl)(μ3-sulfido)*1.5(benzene) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 15.0%

: ruthenium(molybdenum)2(carbonyl)7(cyclopentadienyl)2(μ3-sulfido)

: 536-74-3
phenylacetylene

: 110096-38-3
(molybdenum)2(ruthenium)(carbonyl)2(cyclopentadienyl)2(μ3-η6-1,3,5-triphenylhexatrienyl)(μ3-sulfido)*1.5(benzene)

: Mo2Ru(CO)2Cp2{μ3-η3-HCC(Ph)CH}{μ-η3-PhCC(H)C(Ph)}(μ3-S)

Guidance literature:: In n-heptane; RuMo2-cluster was refluxed in heptane with an excess of PhCCH under N2 for 80 min; evapd., residue was dissolved in CH2Cl2 and chromd. by TLC on SiO2 with hexane-CH2Cl2 as eluent; elem. anal. for RuMo2(CO)2(C5H5)2(μ3-S)(μ3-η6-HCCPhCHCPhCHCPh);
DOI:10.1021/om00153a036

Reference yield: 78.0%

: 110096-38-3
(molybdenum)2(ruthenium)(carbonyl)2(cyclopentadienyl)2(μ3-η6-1,3,5-triphenylhexatrienyl)(μ3-sulfido)*1.5(benzene)

: ruthenium(molybdenum)2(carbonyl)7(cyclopentadienyl)2(μ3-sulfido)

: 612-71-5
1,3,5-triphenylbenzene

Guidance literature:: With carbon monoxide; In not given; 100°C, 25 atm of CO, 3 h; 1,3,5-C6H3Ph3 was identified by its mass and (1)H NMR spectra;
DOI:10.1021/om00153a036

Reference yield: 78.0%

: 110096-38-3
(molybdenum)2(ruthenium)(carbonyl)2(cyclopentadienyl)2(μ3-η6-1,3,5-triphenylhexatrienyl)(μ3-sulfido)*1.5(benzene)

: 110096-39-4
(molybdenum)2(ruthenium)(carbonyl)2(cyclopentadienyl)2(μ-η3-PhCC(H)C(Ph))(μ3-η3.-HCC(Ph)CH)(μ3-sulfido)*0.6(C6H6)

: 112219-90-6
(molybdenum)2(ruthenium)(carbonyl)2(cyclopentadienyl)2(μ-η3-HCC(Ph)CPh)(μ3-η3-HCC(Ph)CH)(μ3-sulfido)*2(benzene)

: ruthenium(molybdenum)2(carbonyl)7(cyclopentadienyl)2(μ3-sulfido)

: 612-71-5
1,3,5-triphenylbenzene

Guidance literature:: With CO; In n-heptane; Mo2Ru(CO)2(C5H5)2(μ3-η6-HCC(Ph)CHC(Ph)CHC(Ph))(μ3-S) pressurized with CO in heptane under 25 atm at 98°C for 3 h; after cooling solvent is removed, residue is dissolved (CH2Cl2), chromd. (TLC); mass spectrum, (1)H-NMR;
DOI:10.1021/om00093a030