N-[2-(phenylseleno)ethyl]morpholine

Base Information

• Chemical Name: N-[2-(phenylseleno)ethyl]morpholine
• CAS No.: 1237031-22-9
• Molecular Formula: C₁₂H₁₇NOSe
• Molecular Weight: 270.233
• Mol file: 1237031-22-9.mol

Synonyms:N-[2-(phenylseleno)ethyl]morpholine

Chemical Property of N-[2-(phenylseleno)ethyl]morpholine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-[2-(phenylseleno)ethyl]morpholine

There total 1 articles about N-[2-(phenylseleno)ethyl]morpholine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

diphenyl diselenide (1666-13-3) + 4-(2-chloroethyl)morpholine hydrochride (3647-69-6) → N-[2-(phenylseleno)ethyl]morpholine (1237031-22-9)

Guidance literature:

diphenyl diselenide; With sodium tetrahydroborate; sodium hydroxide; In ethanol; water; at 20 ℃; Inert atmosphere;

4-(2-chloroethyl)morpholine hydrochride; In ethanol; water;

DOI:10.1016/j.inoche.2010.05.014

Reference yield: 85.0%

rhodium(III) chloride monohydrate (10049-07-7) + N-[2-(phenylseleno)ethyl]morpholine (1237031-22-9) + silver perchlorate → dichlorotetrakis(N-(2-(phenylseleno)ethyl)morpholine)rhodium(III) perchlorate (1237031-16-1)

Guidance literature:

In ethanol; byproducts: AgCl; equimol., stirred for 3-4 h; filtered, concd. (vac.), diethyl ether added, concd., ppt. filtered, washed (diethyl ether), dried (vac.); elem. anal.;

DOI:10.1016/j.inoche.2010.05.014

Reference yield: 80.0%

ammonium hexafluorophosphate + N-[2-(phenylseleno)ethyl]morpholine (1237031-22-9) + [ruthenium(II)(η6-p-cymene)(μ-cloride)chloride]2 (128706-72-9,658044-18-9,52462-29-0) → [ruthenium(II)chloride(η6-p-cymene)(N-[2-(phenylseleno)ethyl]morpholine)](hexafluorophosphate) (1253586-74-1)

Guidance literature:

In methanol; Ru complex (0.1 mmol) added to soln. of NC5H4SeC2H4NC4H8O (0.2 mmol), stirred for 15 h at room temp., filtered, concd., NH4PH6 (0.2 mmol) added; ppt. filtered off, washed with MeOH, dried in vac.; elem. anal.;

DOI:10.1002/ejic.201000319

upstream raw materials:

diphenyl diselenide

4-(2-chloroethyl)morpholine hydrochride

Downstream raw materials:

dichlorotetrakis(N-(2-(phenylseleno)ethyl)morpholine)rhodium(III) perchlorate

[ruthenium(II)chloride(η6-p-cymene)(N-[2-(phenylseleno)ethyl]morpholine)](hexafluorophosphate)

[ruthenium(II)chloride(η6-benzene)(N-[2-(phenylseleno)ethyl]morpholine)](hexafluorophosphate)