5-benzyloxycarbonylamino-5-deoxy-1,2-O-isopropylidene-α-D-glycero-D-gluco-hepto-1,4-furanose

Base Information

• Chemical Name: 5-benzyloxycarbonylamino-5-deoxy-1,2-O-isopropylidene-α-D-glycero-D-gluco-hepto-1,4-furanose
• CAS No.: 1224467-52-0
• Molecular Formula: C₁₈H₂₅NO₈
• Molecular Weight: 383.398
• Mol file: 1224467-52-0.mol

Synonyms:5-benzyloxycarbonylamino-5-deoxy-1,2-O-isopropylidene-α-D-glycero-D-gluco-hepto-1,4-furanose

Chemical Property of 5-benzyloxycarbonylamino-5-deoxy-1,2-O-isopropylidene-α-D-glycero-D-gluco-hepto-1,4-furanose

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5-benzyloxycarbonylamino-5-deoxy-1,2-O-isopropylidene-α-D-glycero-D-gluco-hepto-1,4-furanose

There total 1 articles about 5-benzyloxycarbonylamino-5-deoxy-1,2-O-isopropylidene-α-D-glycero-D-gluco-hepto-1,4-furanose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

5-azido-3-O-benzyl-5-deoxy-1,2-O-isopropylidene-α-D-glycero-D-gluco-hepto-1,4-furanose (1224467-46-2) + benzyl chloroformate (501-53-1,94274-21-2) → 5-benzyloxycarbonylamino-5-deoxy-1,2-O-isopropylidene-α-D-glycero-D-gluco-hepto-1,4-furanose (1224467-52-0)

Guidance literature:

5-azido-3-O-benzyl-5-deoxy-1,2-O-isopropylidene-α-D-glycero-D-gluco-hepto-1,4-furanose; With palladium 10% on activated carbon; ammonium formate; In methanol; for 1h; Reflux; Inert atmosphere;

benzyl chloroformate; With sodium hydrogencarbonate; In methanol; water; at 0 ℃; for 18h; Inert atmosphere;

DOI:10.1016/j.tetasy.2010.01.007

Reference yield:

5-benzyloxycarbonylamino-5-deoxy-1,2-O-isopropylidene-α-D-glycero-D-gluco-hepto-1,4-furanose (1224467-52-0) → C17H21NO7

Guidance literature:

With sodium periodate; In water; acetone; for 1.5h; Cooling; Inert atmosphere;

DOI:10.1016/j.tetasy.2010.01.007

upstream raw materials:

5-azido-3-O-benzyl-5-deoxy-1,2-O-isopropylidene-α-D-glycero-D-gluco-hepto-1,4-furanose

benzyl chloroformate