tert-butyl (E)-3-methyl-7-phenylhept-2-en-6-ynyl carbonate

Base Information

• Chemical Name: tert-butyl (E)-3-methyl-7-phenylhept-2-en-6-ynyl carbonate
• CAS No.: 1226869-15-3
• Molecular Formula: C₁₉H₂₄O₃
• Molecular Weight: 300.398
• Mol file: 1226869-15-3.mol

Synonyms:tert-butyl (E)-3-methyl-7-phenylhept-2-en-6-ynyl carbonate

Chemical Property of tert-butyl (E)-3-methyl-7-phenylhept-2-en-6-ynyl carbonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tert-butyl (E)-3-methyl-7-phenylhept-2-en-6-ynyl carbonate

There total 1 articles about tert-butyl (E)-3-methyl-7-phenylhept-2-en-6-ynyl carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

C14H16O (1227303-72-1) + {[(tert-butoxycarbonyl)oxy]amino}(phenyl)acetonitrile (80994-44-1) → tert-butyl (E)-3-methyl-7-phenylhept-2-en-6-ynyl carbonate (1226869-15-3)

Guidance literature:

C₁₄H₁₆O; With n-butyllithium; In diethyl ether; hexane; at -78 ℃; for 0.5h;

{[(tert-butoxycarbonyl)oxy]amino}(phenyl)acetonitrile; In tetrahydrofuran; diethyl ether; hexane; at 0 - 20 ℃;

DOI:10.5012/bkcs.2010.31.03.670

Reference yield: 60.0%

tert-butyl (E)-3-methyl-7-phenylhept-2-en-6-ynyl carbonate (1226869-15-3) → C15H15IO3 + C19H24BrIO3

Guidance literature:

With iodine(I) bromide; In dichloromethane; at -78 ℃; diastereoselective reaction;

DOI:10.5012/bkcs.2010.31.03.670

Reference yield: 58.0%

tert-butyl (E)-3-methyl-7-phenylhept-2-en-6-ynyl carbonate (1226869-15-3) → C15H16O3

Guidance literature:

With silver hexafluoroantimonate; 2-(di-tert-butylphosphino)-1,1'-biphenylgold(I) chloride; In 1,2-dichloro-ethane; at 20 ℃; diastereoselective reaction;

DOI:10.5012/bkcs.2010.31.03.670

upstream raw materials:

C₁₄H₁₆O

{[(tert-butoxycarbonyl)oxy]amino}(phenyl)acetonitrile

Refernces