2,6,7-Trioxa-1-phosphabicyclo(2.2.2)octane, 4-(2-propenyl)-, 1-oxide

Base Information

Chemical Name:2,6,7-Trioxa-1-phosphabicyclo(2.2.2)octane, 4-(2-propenyl)-, 1-oxide
CAS No.:80479-47-6
Molecular Formula:C₇H₁₁O₄P
Molecular Weight:190.136
Hs Code.:
DSSTox Substance ID:DTXSID10230356
Wikidata:Q83110870

Synonyms:2,6,7-Trioxa-1-phosphabicyclo(2.2.2)octane, 4-(2-propenyl)-, 1-oxide;4-(2-Propenyl)-2,6,7-trioxa-1-phosphabicyclo(2.2.2)octane 1-oxide;1,3-Propanediol, 2-allyl-2-(hydroxymethyl)-, cyclic phosphate (1:1);80479-47-6;DTXSID10230356;LS-157672

Suppliers and Price of 2,6,7-Trioxa-1-phosphabicyclo(2.2.2)octane, 4-(2-propenyl)-, 1-oxide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2,6,7-Trioxa-1-phosphabicyclo(2.2.2)octane, 4-(2-propenyl)-, 1-oxide

Chemical Property:

Vapor Pressure:0.109mmHg at 25°C
Boiling Point:228.6°C at 760 mmHg
Flash Point:106.2°C
Density:1.28g/cm³
XLogP3:0.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:2
Exact Mass:190.03949583
Heavy Atom Count:12
Complexity:219

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C=CCC12COP(=O)(OC1)OC2

Technology Process of 2,6,7-Trioxa-1-phosphabicyclo(2.2.2)octane, 4-(2-propenyl)-, 1-oxide

There total 3 articles about 2,6,7-Trioxa-1-phosphabicyclo(2.2.2)octane, 4-(2-propenyl)-, 1-oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 27.0%

: 27606-27-5
2-hydroxymethyl-2-(prop-2-enyl)propan-1,3-diol

: 80479-47-6
4-Allyl-2,6,7-trioxa-1-phospha-bicyclo[2.2.2]octane 1-oxide

Guidance literature:: With pyridine; trichlorophosphate; In acetonitrile;
DOI:10.1271/bbb1961.46.411

Reference yield:

: 2049-80-1
(2-propenyl)propanedioic acid diethyl ester

: 80479-47-6
4-Allyl-2,6,7-trioxa-1-phospha-bicyclo[2.2.2]octane 1-oxide

Guidance literature:: Multi-step reaction with 3 steps

1: 13 percent / K₂CO₃ / dimethylsulfoxide / 168 h / Ambient temperature

2: 7 percent / LiAlH₄ / diethyl ether / Ambient temperature

3: 27 percent / POCl₃, pyridine / acetonitrile

With pyridine; lithium aluminium tetrahydride; potassium carbonate; trichlorophosphate; In diethyl ether; dimethyl sulfoxide; acetonitrile;
DOI:10.1271/bbb1961.46.411

Reference yield:

: 82515-47-7
diethyl 2-allyl-2-(hydroxymethyl)malonate

: 80479-47-6
4-Allyl-2,6,7-trioxa-1-phospha-bicyclo[2.2.2]octane 1-oxide

Guidance literature:: Multi-step reaction with 2 steps

1: 7 percent / LiAlH₄ / diethyl ether / Ambient temperature

2: 27 percent / POCl₃, pyridine / acetonitrile

With pyridine; lithium aluminium tetrahydride; trichlorophosphate; In diethyl ether; acetonitrile;
DOI:10.1271/bbb1961.46.411