Hydramethylnon

Base Information

• Chemical Name: Hydramethylnon
• CAS No.: 67485-29-4
• Deprecated CAS: 70829-12-8
• Molecular Formula: C₂₅H₂₄F₆N₄
• Molecular Weight: 494.483
• Hs Code.: 2933599017
• European Community (EC) Number: 405-090-9,614-073-7
• UNII: J265GZ7MFJ
• UN Number: 3077,2588
• ChEMBL ID: CHEMBL464812
• Metabolomics Workbench ID: 52957
• Nikkaji Number: J125.937G
• NSC Number: 379665
• Wikidata: Q413481
• Wikipedia: Hydramethylnon
• Mol file: 67485-29-4.mol

Synonyms:AC 217,300;AC-217300;Amdro;hydramethylnon;hydromethylnon

Chemical Property of Hydramethylnon

Chemical Property:

• Appearance/Colour: Odorless yellow crystals
• Vapor Pressure: 1.54E-10mmHg at 25°C
• Melting Point: 185-190 °C
• Refractive Index: 1.526
• Boiling Point: 510.5 °C at 760 mmHg
• PKA: 14.38±0.40(Predicted)
• Flash Point: 262.6 °C
• PSA: 48.78000
• Density: 1.23 g/cm³
• LogP: 7.03940
• Storage Temp.: 0-6°C
• Water Solubility.: 0.005-0.007 mg l-1(25 °C)
• XLogP3: 6.4
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 6
• Exact Mass: 494.19051575
• Heavy Atom Count: 35
• Complexity: 763
• Transport DOT Label: Class 9

Purity/Quality:

99% ^*data from raw suppliers

Hydramethylon ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T; N
• Hazard Codes: T;N,N,T
• Statements: 22-36-48/25-50/53
• Safety Statements: 1/2-22-26-36/37-45-60-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Pesticides -> Other Insecticides
• Canonical SMILES: CC1(CNC(=NC1)NN=C(C=CC2=CC=C(C=C2)C(F)(F)F)C=CC3=CC=C(C=C3)C(F)(F)F)C
• Isomeric SMILES: CC1(CN=C(NC1)NN=C(/C=C/C2=CC=C(C=C2)C(F)(F)F)/C=C/C3=CC=C(C=C3)C(F)(F)F)C
• Description: Hydramethylnon is an organic pesticide active ingredient from the trifluoromethyl aminohydrazone chemical class. It is a registered chemical alternative for chlorpyrifos for use as a termiticide and against ants, crickets, and cockroaches around the home and lawn. Hydramethylnon is also used in a wide variety of professional pesticide products and in various formulations, These include foaming products, granular products, gel baits, liquid concentrates.
• Uses: Hydramethylon is an insecticide primarily used in the form of baits for cockroaches and ants.

Technology Process of Hydramethylnon

There total 3 articles about Hydramethylnon which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

1,5-bis(4-trifluoromethylphenyl)-1,4-pentadiene-3-one (103836-71-1,103836-73-3,103836-74-4,42160-07-6) + 2-hydrazino-5,5-dimethyl-1,4,5,6-tetrahydropyrimidine hydrochloride → hydramethylnon (67485-29-4,120167-29-5,120167-32-0)

Guidance literature:

With sulfuric acid; In methanol; water; for 5h; Reagent/catalyst; Time; Reflux;

Reference yield:

5,5-dimethyl-1,4,5,6,-tetrahydropyridinium-2-ylhydrazine hydroiodide + 1,5-bis(α,α,α-trifluoro-p-tolyl)-1,4-pentadien-3-one (103836-71-1) → N-[1,5-bis[4-(trifluoromethyl)phenyl]penta-1,4-dien-3-ylideneamino]-5,5-dimethyl-4,6-dihydro-1H-pyrimidin-2-amine (67485-29-4,120167-29-5,120167-32-0)

Guidance literature:

With hydrogen iodide; In ethanol; ethyl acetate;

Reference yield:

→ N-[1,5-bis[4-(trifluoromethyl)phenyl]penta-1,4-dien-3-ylideneamino]-5,5-dimethyl-4,6-dihydro-1H-pyrimidin-2-amine (67485-29-4,120167-29-5,120167-32-0)

Guidance literature:

5,5-Dimethyl-1,4,5,6-tetrahydropyrimidin-2-ylhydrazinhydroiodid, 1,5-Bis-(α,α,α-trifluor-p-tolyl)-1,4-pentadien-3-on, Na2CO3;

upstream raw materials:

1,5-bis(α,α,α-trifluoro-p-tolyl)-1,4-pentadien-3-one

1,5-bis(4-trifluoromethylphenyl)-1,4-pentadiene-3-one

Refernces

• 1、 -. "Acylated pentadienone hydrazone, method for preparing the same, and use as fire ant control agents". . . Retrieved 2008/06/13.
• 2、 -. "Pentadienone hydrazones as insecticides". . . Retrieved 2008/06/13.