2-(3-{2-[(2E,4E)-9-(4-Methoxy-benzyloxy)-nona-2,4-dienyl]-[1,3]dithian-2-yl}-propoxy)-tetrahydro-pyran

Base Information

Chemical Name:2-(3-{2-[(2E,4E)-9-(4-Methoxy-benzyloxy)-nona-2,4-dienyl]-[1,3]dithian-2-yl}-propoxy)-tetrahydro-pyran
CAS No.:383863-66-9
Molecular Formula:C₂₉H₄₄O₄S₂
Molecular Weight:520.798
Hs Code.:

Synonyms:2-(3-{2-[(2E,4E)-9-(4-Methoxy-benzyloxy)-nona-2,4-dienyl]-[1,3]dithian-2-yl}-propoxy)-tetrahydro-pyran

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Chemical Property of 2-(3-{2-[(2E,4E)-9-(4-Methoxy-benzyloxy)-nona-2,4-dienyl]-[1,3]dithian-2-yl}-propoxy)-tetrahydro-pyran

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Technology Process of 2-(3-{2-[(2E,4E)-9-(4-Methoxy-benzyloxy)-nona-2,4-dienyl]-[1,3]dithian-2-yl}-propoxy)-tetrahydro-pyran

There total 12 articles about 2-(3-{2-[(2E,4E)-9-(4-Methoxy-benzyloxy)-nona-2,4-dienyl]-[1,3]dithian-2-yl}-propoxy)-tetrahydro-pyran which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 139230-31-2
2-(3-(1,3-dithian-2-yl)propoxy)tetrahydro-2H-pyran

: 177977-00-3
1-((5E,7E)-9-Chloro-nona-5,7-dienyloxymethyl)-4-methoxy-benzene

: 383863-66-9
2-(3-{2-[(2E,4E)-9-(4-Methoxy-benzyloxy)-nona-2,4-dienyl]-[1,3]dithian-2-yl}-propoxy)-tetrahydro-pyran

Guidance literature:: With n-butyllithium; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; 1.) -25 deg C, 4 h, 2.) -78 deg C to r.t., 20 h;

Reference yield:

: 53178-48-6
2-(3'-hydroxypropyl)-1,3-dithiane

: 383863-66-9
2-(3-{2-[(2E,4E)-9-(4-Methoxy-benzyloxy)-nona-2,4-dienyl]-[1,3]dithian-2-yl}-propoxy)-tetrahydro-pyran

Guidance literature:: Multi-step reaction with 2 steps

1.1: 99.3 percent / camphorsulfonic acid / CH₂Cl₂ / 2 h / 0 °C

2.1: n-BuLi / hexane; tetrahydrofuran / 4 h / -25 °C

2.2: HMPA / hexane; tetrahydrofuran / 20 h / -78 - 20 °C

With n-butyllithium; camphor-10-sulfonic acid; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1002/1521-3765(20011001)7:19<4107::AID-CHEM4107>3.0.CO;2-K

Reference yield:

: 131375-63-8
5-(4-methoxybenzyloxy)-1-pentanol

: 383863-66-9
2-(3-{2-[(2E,4E)-9-(4-Methoxy-benzyloxy)-nona-2,4-dienyl]-[1,3]dithian-2-yl}-propoxy)-tetrahydro-pyran

Guidance literature:: Multi-step reaction with 5 steps

1.1: 89.5 percent / (COCl)2; DMSO; Et₃N / CH₂Cl₂ / 0.92 h / -78 - 0 °C

2.1: LDA / hexane; tetrahydrofuran / 0.5 h / -78 °C

2.2: 70 percent / HMPA / hexane; tetrahydrofuran / 24 h / -78 - 20 °C

3.1: 97.6 percent / DIBALH / toluene; hexane / 0.33 h / -15 °C

4.1: n-BuLi / hexane; tetrahydrofuran / 0.5 h / -15 °C

4.2: MsCl / hexane; tetrahydrofuran / 20 h / -15 - 20 °C

5.1: n-BuLi / hexane; tetrahydrofuran / 4 h / -25 °C

5.2: HMPA / hexane; tetrahydrofuran / 20 h / -78 - 20 °C

With n-butyllithium; oxalyl dichloride; diisobutylaluminium hydride; dimethyl sulfoxide; triethylamine; lithium diisopropyl amide; In tetrahydrofuran; hexane; dichloromethane; toluene; 1.1: Swern oxidation / 2.2: Horner-Wadsworth-Emmons reaction;
DOI:10.1002/1521-3765(20011001)7:19<4107::AID-CHEM4107>3.0.CO;2-K