4-<(metoxycarbonyl)methyl>thio-5-nitro-1-(2,3,5-tri-O-benzoyl-β-D-ribofuranosyl)imidazole

Base Information

Chemical Name:4-<(metoxycarbonyl)methyl>thio-5-nitro-1-(2,3,5-tri-O-benzoyl-β-D-ribofuranosyl)imidazole
CAS No.:129548-72-7
Molecular Formula:C₃₂H₂₇N₃O₁₁S
Molecular Weight:661.646
Hs Code.:

Synonyms:4-<(metoxycarbonyl)methyl>thio-5-nitro-1-(2,3,5-tri-O-benzoyl-β-D-ribofuranosyl)imidazole

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Chemical Property of 4-<(metoxycarbonyl)methyl>thio-5-nitro-1-(2,3,5-tri-O-benzoyl-β-D-ribofuranosyl)imidazole

Chemical Property:

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Technology Process of 4-<(metoxycarbonyl)methyl>thio-5-nitro-1-(2,3,5-tri-O-benzoyl-β-D-ribofuranosyl)imidazole

There total 1 articles about 4-<(metoxycarbonyl)methyl>thio-5-nitro-1-(2,3,5-tri-O-benzoyl-β-D-ribofuranosyl)imidazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 6974-32-9
1-O-acetyl-2,3,5-tri-O-benzoyl-β-D-ribofuranose

: 129548-71-6
4(5)-thio-5(4)-nitroimidazole

: 129548-73-8
5-<(metoxycarbonyl)methyl>thio-4-nitro-1-(2,3,5-tri-O-benzoyl-β-D-ribofuranosyl)imidazole

: 129548-72-7
4-<(metoxycarbonyl)methyl>thio-5-nitro-1-(2,3,5-tri-O-benzoyl-β-D-ribofuranosyl)imidazole

Guidance literature:: With chloro-trimethyl-silane; trimethylsilyl trifluoromethanesulfonate; Yield given. Multistep reaction. Yields of byproduct given; 1) HMDS, xylene, 130 deg C, 1h, 2) CH₃CN, 90 s;
DOI:10.1039/P19900000955

Reference yield: 73.0%

: 129548-72-7
4-<(metoxycarbonyl)methyl>thio-5-nitro-1-(2,3,5-tri-O-benzoyl-β-D-ribofuranosyl)imidazole

: 129548-74-9
4-<(metoxycarbonyl)methyl>sulphonyl-5-nitro-1-(2,3,5-tri-O-benzoyl-β-D-ribofuranosyl)imidazole

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 20 ℃; for 19h;
DOI:10.1039/P19900000955

Reference yield:

: 129548-72-7
4-<(metoxycarbonyl)methyl>thio-5-nitro-1-(2,3,5-tri-O-benzoyl-β-D-ribofuranosyl)imidazole

: 129548-75-0
5-amino-4-<(metoxycarbonyl)methyl>sulphonyl-1-(2,3,5-tri-O-benzoyl-β-D-ribofuranosyl)imidazole

Guidance literature:: Multi-step reaction with 2 steps

1: 73 percent / m-chloroperbenzoic acid / CH₂Cl₂ / 19 h / 20 °C

2: 97 percent / H₂ / Pd/C / ethyl acetate / 20 °C

With hydrogen; 3-chloro-benzenecarboperoxoic acid; palladium on activated charcoal; In dichloromethane; ethyl acetate;
DOI:10.1039/P19900000955