(2(1')Z,2'Z)-1,1-dimethyl-3-methylene-2-(butenylidene)cyclohexane

Base Information

• Chemical Name: (2(1')Z,2'Z)-1,1-dimethyl-3-methylene-2-(butenylidene)cyclohexane
• CAS No.: 116205-44-8
• Molecular Formula: C₁₃H₂₀
• Molecular Weight: 177.294
• Mol file: 116205-44-8.mol

Synonyms:(2(1')Z,2'Z)-1,1-dimethyl-3-methylene-2-(butenylidene)cyclohexane

Chemical Property of (2(1')Z,2'Z)-1,1-dimethyl-3-methylene-2-(butenylidene)cyclohexane

Chemical Property:

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Technology Process of (2(1')Z,2'Z)-1,1-dimethyl-3-methylene-2-(butenylidene)cyclohexane

There total 2 articles about (2(1')Z,2'Z)-1,1-dimethyl-3-methylene-2-(butenylidene)cyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(2(1')Z,2'E)-1,1-dimethyl-3-methylene-2-(3'-(phenylsulfinyl)-2'-butenylidene)cyclohexane (103149-82-2) → (2(1')Z,2'Z)-1,1-dimethyl-3-methylene-2-(butenylidene)cyclohexane (116205-44-8)

Guidance literature:

With deuteromethanol; tert.-butyl lithium; In diethyl ether; at -78 ℃; for 0.166667h; Yield given;

DOI:10.1021/jo00289a059

Reference yield:

(2(1')Z,2'E)-1,1-dimethyl-3-methylene-2-(3'-(phenylsulfinyl)-2'-butenylidene)cyclohexane (103149-82-2) → (tert-butylsulfinyl)benzene (62076-10-2,4170-71-2) + (2(1')Z,2'Z)-1,1-dimethyl-3-methylene-2-(butenylidene)cyclohexane (116205-44-8)

Guidance literature:

With deuteromethanol; tert.-butyl lithium; Yield given. Multistep reaction; 1.) pentane, ether, -78 deg C, 10 min;

DOI:10.1016/S0040-4039(00)96914-4

upstream raw materials:

(2(1')Z,2'E)-1,1-dimethyl-3-methylene-2-(3'-(phenylsulfinyl)-2'-butenylidene)cyclohexane