Technology Process of 1L-(1,2,4,6/3,5)-6-benzoyloxymethyl-1,2-O-cyclohexylidene-1,2,3,4,5-cyclohexanepentol
There total 5 articles about 1L-(1,2,4,6/3,5)-6-benzoyloxymethyl-1,2-O-cyclohexylidene-1,2,3,4,5-cyclohexanepentol which
guide to synthetic route it.
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synthetic route:
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1L-(1,2,4,6/3,5)-6-benzoyloxymethyl-1,2:3,4-di-O-cyclohexylidene-5-O-methyl-1,2,3,4,5-cyclohexanepentol
- Guidance literature:
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With
aluminium trichloride; sodium iodide;
In
acetonitrile;
for 3h;
Ambient temperature;
DOI:10.1246/bcsj.66.3760
- Guidance literature:
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Multi-step reaction with 5 steps
1: 76 percent / tetrahydrofuran; diethyl ether / 9 h / Ambient temperature
2: 76 percent / KH / tetrahydrofuran / 3 h / Ambient temperature
3: 1.) BH3, 2.) 3 mol/dm3 aq. NaOH, 30percent H2O2 / 1.) THF, RT, 5 h, 2.) THF, 50 deg C, 1 h
4: pyridine, 4-dimethylaminopyridine / Ambient temperature
5: 61 percent / NaI, AlCl3 / acetonitrile / 3 h / Ambient temperature
With
pyridine; dmap; sodium hydroxide; aluminium trichloride; borane; dihydrogen peroxide; potassium hydride; sodium iodide;
In
tetrahydrofuran; diethyl ether; acetonitrile;
DOI:10.1246/bcsj.66.3760
- Guidance literature:
-
Multi-step reaction with 2 steps
1: pyridine, 4-dimethylaminopyridine / Ambient temperature
2: 61 percent / NaI, AlCl3 / acetonitrile / 3 h / Ambient temperature
With
pyridine; dmap; aluminium trichloride; sodium iodide;
In
acetonitrile;
DOI:10.1246/bcsj.66.3760
