C₃₄H₃₆O₁₃

Base Information

• Chemical Name: C₃₄H₃₆O₁₃
• CAS No.: 861114-21-8
• Molecular Formula: C₃₄H₃₆O₁₃
• Molecular Weight: 652.652
• Mol file: 861114-21-8.mol

Synonyms:C₃₄H₃₆O₁₃

Chemical Property of C₃₄H₃₆O₁₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₄H₃₆O₁₃

There total 24 articles about C₃₄H₃₆O₁₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C37H58O11Si2 (861113-98-6) → C34H36O13 (861114-21-8)

Guidance literature:

Multi-step reaction with 16 steps

1.1: 96 percent / K₂OsO₄*2H₂O; (DHQD)2PHAL; MeSO₂NH₂ / K₃Fe(CN)6; K₂CO₃ / 2-methyl-propan-2-ol; H₂O / 2 h

2.1: 98 percent / Et₃N; DMAP / CH₂Cl₂ / 8 h / 0 - 25 °C

3.1: H₂ / Pd(OH)2/C / methanol; H₂O / 2 h / 25 °C / pH 7

4.1: base

5.1: NaBH₄ / methanol / 0.5 h / 0 - 25 °C

6.1: Pb(OAc)4 / CH₂Cl₂ / 2 h / 0 - 25 °C

7.1: 70 percent / DBU / toluene / 4 h / Heating

8.1: SOCl₂; pyridine / 8 h / 0 - 25 °C

8.2: K₂CO₃; MeOH / 2 h / 25 °C

9.1: Br₂; N,N-dimethylaniline; K₂CO₃ / CH₂Cl₂ / 0.17 h / -78 °C

9.2: 76 percent / N,N-dimethylaniline; K₂CO₃ / CH₂Cl₂ / 3 h / -78 - 0 °C

10.1: 42 percent / (Me₃Si)3SiH; AIBN / toluene / 0.5 h / 110 °C

11.1: 88 percent / NaBH₄ / methanol / 0.25 h / 0 °C

12.1: pyridine; DMAP / 5 h / 60 °C

13.1: HCl / methanol; diethyl ether / 4 h / 0 - 25 °C

14.1: 79 percent / Et₃N; DMAP / CH₂Cl₂ / 6 h / 0 - 25 °C

15.1: H₂SO₄ / CH₂Cl₂ / 0.5 h / 0 °C

16.1: PCC / 1,2-dichloro-ethane / 16 h / 65 °C

With pyridine; lead(IV) acetate; hydrogenchloride; dmap; sodium tetrahydroborate; potassium osmate(VI); thionyl chloride; 2,2'-azobis(isobutyronitrile); methanesulfonamide; tris-(trimethylsilyl)silane; sulfuric acid; hydrogen; bromine; potassium carbonate; N,N-dimethyl-aniline; 1,8-diazabicyclo[5.4.0]undec-7-ene; 1,4-bis(9-O-dihydroquinidine)phthalazine; triethylamine; pyridinium chlorochromate; palladium dihydroxide; potassium carbonate; potassium hexacyanoferrate(III); In methanol; diethyl ether; dichloromethane; water; 1,2-dichloro-ethane; toluene; tert-butyl alcohol;

DOI:10.1002/anie.200500217

Reference yield:

C38H57F3O14SSi2 (861113-97-5) → C34H36O13 (861114-21-8)

Guidance literature:

Multi-step reaction with 17 steps

1.1: 95 percent / Et₃SiH; Pd(PPh₃)4; LiCl / dimethylformamide / 24 h / 55 °C

2.1: 96 percent / K₂OsO₄*2H₂O; (DHQD)2PHAL; MeSO₂NH₂ / K₃Fe(CN)6; K₂CO₃ / 2-methyl-propan-2-ol; H₂O / 2 h

3.1: 98 percent / Et₃N; DMAP / CH₂Cl₂ / 8 h / 0 - 25 °C

4.1: H₂ / Pd(OH)2/C / methanol; H₂O / 2 h / 25 °C / pH 7

5.1: base

6.1: NaBH₄ / methanol / 0.5 h / 0 - 25 °C

7.1: Pb(OAc)4 / CH₂Cl₂ / 2 h / 0 - 25 °C

8.1: 70 percent / DBU / toluene / 4 h / Heating

9.1: SOCl₂; pyridine / 8 h / 0 - 25 °C

9.2: K₂CO₃; MeOH / 2 h / 25 °C

10.1: Br₂; N,N-dimethylaniline; K₂CO₃ / CH₂Cl₂ / 0.17 h / -78 °C

10.2: 76 percent / N,N-dimethylaniline; K₂CO₃ / CH₂Cl₂ / 3 h / -78 - 0 °C

11.1: 42 percent / (Me₃Si)3SiH; AIBN / toluene / 0.5 h / 110 °C

12.1: 88 percent / NaBH₄ / methanol / 0.25 h / 0 °C

13.1: pyridine; DMAP / 5 h / 60 °C

14.1: HCl / methanol; diethyl ether / 4 h / 0 - 25 °C

15.1: 79 percent / Et₃N; DMAP / CH₂Cl₂ / 6 h / 0 - 25 °C

16.1: H₂SO₄ / CH₂Cl₂ / 0.5 h / 0 °C

17.1: PCC / 1,2-dichloro-ethane / 16 h / 65 °C

With pyridine; lead(IV) acetate; hydrogenchloride; triethylsilane; dmap; sodium tetrahydroborate; potassium osmate(VI); tetrakis(triphenylphosphine) palladium⁽⁰⁾; thionyl chloride; 2,2'-azobis(isobutyronitrile); methanesulfonamide; tris-(trimethylsilyl)silane; sulfuric acid; hydrogen; bromine; potassium carbonate; N,N-dimethyl-aniline; 1,8-diazabicyclo[5.4.0]undec-7-ene; 1,4-bis(9-O-dihydroquinidine)phthalazine; triethylamine; pyridinium chlorochromate; lithium chloride; palladium dihydroxide; potassium carbonate; potassium hexacyanoferrate(III); In methanol; diethyl ether; dichloromethane; water; 1,2-dichloro-ethane; N,N-dimethyl-formamide; toluene; tert-butyl alcohol;

DOI:10.1002/anie.200500217

Reference yield:

C37H60O13Si2 (861113-99-7) → C34H36O13 (861114-21-8)

Guidance literature:

Multi-step reaction with 15 steps

1.1: 98 percent / Et₃N; DMAP / CH₂Cl₂ / 8 h / 0 - 25 °C

2.1: H₂ / Pd(OH)2/C / methanol; H₂O / 2 h / 25 °C / pH 7

3.1: base

4.1: NaBH₄ / methanol / 0.5 h / 0 - 25 °C

5.1: Pb(OAc)4 / CH₂Cl₂ / 2 h / 0 - 25 °C

6.1: 70 percent / DBU / toluene / 4 h / Heating

7.1: SOCl₂; pyridine / 8 h / 0 - 25 °C

7.2: K₂CO₃; MeOH / 2 h / 25 °C

8.1: Br₂; N,N-dimethylaniline; K₂CO₃ / CH₂Cl₂ / 0.17 h / -78 °C

8.2: 76 percent / N,N-dimethylaniline; K₂CO₃ / CH₂Cl₂ / 3 h / -78 - 0 °C

9.1: 42 percent / (Me₃Si)3SiH; AIBN / toluene / 0.5 h / 110 °C

10.1: 88 percent / NaBH₄ / methanol / 0.25 h / 0 °C

11.1: pyridine; DMAP / 5 h / 60 °C

12.1: HCl / methanol; diethyl ether / 4 h / 0 - 25 °C

13.1: 79 percent / Et₃N; DMAP / CH₂Cl₂ / 6 h / 0 - 25 °C

14.1: H₂SO₄ / CH₂Cl₂ / 0.5 h / 0 °C

15.1: PCC / 1,2-dichloro-ethane / 16 h / 65 °C

With pyridine; lead(IV) acetate; hydrogenchloride; dmap; sodium tetrahydroborate; thionyl chloride; 2,2'-azobis(isobutyronitrile); tris-(trimethylsilyl)silane; sulfuric acid; hydrogen; bromine; potassium carbonate; N,N-dimethyl-aniline; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; pyridinium chlorochromate; palladium dihydroxide; In methanol; diethyl ether; dichloromethane; water; 1,2-dichloro-ethane; toluene;

DOI:10.1002/anie.200500217

upstream raw materials:

C₃₄H₃₈O₁₃

C₂₈H₄₈O₁₀Si₂

C₃₀H₅₀O₁₁Si₂

C₃₁H₃₆O₁₁

Downstream raw materials:

C₄₂H₆₀O₁₁Si₂