(2E,4S,5R)-5-tert-butyldiphenylsilyloxy-4,6-dihydroxy-2-hexenal dimethyl acetal

Base Information

Chemical Name:(2E,4S,5R)-5-tert-butyldiphenylsilyloxy-4,6-dihydroxy-2-hexenal dimethyl acetal
CAS No.:136011-39-7
Molecular Formula:C₂₄H₃₄O₅Si
Molecular Weight:430.616
Hs Code.:

Synonyms:(2E,4S,5R)-5-tert-butyldiphenylsilyloxy-4,6-dihydroxy-2-hexenal dimethyl acetal

Suppliers and Price of (2E,4S,5R)-5-tert-butyldiphenylsilyloxy-4,6-dihydroxy-2-hexenal dimethyl acetal

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (2E,4S,5R)-5-tert-butyldiphenylsilyloxy-4,6-dihydroxy-2-hexenal dimethyl acetal

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (2E,4S,5R)-5-tert-butyldiphenylsilyloxy-4,6-dihydroxy-2-hexenal dimethyl acetal

There total 4 articles about (2E,4S,5R)-5-tert-butyldiphenylsilyloxy-4,6-dihydroxy-2-hexenal dimethyl acetal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 136011-38-6
(2E,4S,5R)-5-tert-butyldiphenylsilyloxy-4,6-diacetoxy-2-hexenal dimethyl acetal

: 136011-39-7
(2E,4S,5R)-5-tert-butyldiphenylsilyloxy-4,6-dihydroxy-2-hexenal dimethyl acetal

Guidance literature:: With potassium carbonate; In methanol; for 1h; Ambient temperature;
DOI:10.1055/s-1991-28417

Reference yield:

: 29581-05-3
(2E,4S,5R)-4,6-diacetoxy-5-hydroxy-2(E)-hexenal

: 136011-39-7
(2E,4S,5R)-5-tert-butyldiphenylsilyloxy-4,6-dihydroxy-2-hexenal dimethyl acetal

Guidance literature:: Multi-step reaction with 3 steps

1: p-TsOH, molecular sieves 3 Angstroem / methanol / 24 h / Ambient temperature

2: 62 percent / imidazole / dimethylformamide / 20 h / Ambient temperature

3: 96 percent / K₂CO₃ / methanol / 1 h / Ambient temperature

With 1H-imidazole; 3 A molecular sieve; potassium carbonate; toluene-4-sulfonic acid; In methanol; N,N-dimethyl-formamide;
DOI:10.1055/s-1991-28417

Reference yield:

: 136011-37-5
(2E,4S,5R)-4,6-diacetoxy-5-hydroxy-2-hexenal dimethyl acetal

: 136011-39-7
(2E,4S,5R)-5-tert-butyldiphenylsilyloxy-4,6-dihydroxy-2-hexenal dimethyl acetal

Guidance literature:: Multi-step reaction with 2 steps

1: 62 percent / imidazole / dimethylformamide / 20 h / Ambient temperature

2: 96 percent / K₂CO₃ / methanol / 1 h / Ambient temperature

With 1H-imidazole; potassium carbonate; In methanol; N,N-dimethyl-formamide;
DOI:10.1055/s-1991-28417