[RuCl(η6-p-cymene)(3-phenyl-indenylidene)(PCy3)][CF3SO3]

Base Information

• Chemical Name: [RuCl(η6-p-cymene)(3-phenyl-indenylidene)(PCy3)][CF3SO3]
• CAS No.: 633293-13-7
• Molecular Formula: CF₃O₃S*C₄₃H₅₇ClPRu
• Molecular Weight: 890.493
• Mol file: 633293-13-7.mol

Synonyms:[RuCl(η6-p-cymene)(3-phenyl-indenylidene)(PCy3)][CF3SO3]

Chemical Property of [RuCl(η6-p-cymene)(3-phenyl-indenylidene)(PCy3)][CF3SO3]

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of [RuCl(η6-p-cymene)(3-phenyl-indenylidene)(PCy3)][CF3SO3]

There total 2 articles about [RuCl(η6-p-cymene)(3-phenyl-indenylidene)(PCy3)][CF3SO3] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

(η6-p-cymene)Ru(P(cyclohexyl)3)(CCC(phenyl)2)Cl triflate + trifluorormethanesulfonic acid (1493-13-6) → [RuCl(η6-p-cymene)(3-phenyl-indenylidene)(PCy3)][CF3SO3] (633293-13-7)

Guidance literature:

With aluminum oxide; In dichloromethane; Schlenk technique; triflic acid added to soln. of Ru complex in CH2Cl2 at 213 K, mixt. kept at 248 K for 2 h, cooling to 193 K, addn. of CH2Cl2,stirring with Al2O3 for 15 min; filtration, alumina washed with CH2Cl2, filtrates evapd. to dryness at 243 K, solid washed with pentane/Et2O, dried under vac.;

DOI:10.1021/ja0579762

Reference yield:

(η6-p-cymene)Ru(P(cyclohexyl)3)(CCC(phenyl)2)Cl triflate → [RuCl(η6-p-cymene)(3-phenyl-indenylidene)(PCy3)][CF3SO3] (633293-13-7)

Guidance literature:

In benzene; (Ar); Schlenk technique; soln. of Ru complex in C6H6 was heated at 25-50°C; UV monitoring; Kinetics;

DOI:10.1021/om100654z

upstream raw materials:

trifluorormethanesulfonic acid