dicarbonyl(η5-pentaphenylcycopentadienyl)(tert-butyloxy)ruthenium(II)

Base Information

• Chemical Name: dicarbonyl(η5-pentaphenylcycopentadienyl)(tert-butyloxy)ruthenium(II)
• CAS No.: 860009-16-1
• Molecular Formula: C₄₁H₃₄O₃Ru
• Molecular Weight: 675.789
• Mol file: 860009-16-1.mol

Synonyms:dicarbonyl(η5-pentaphenylcycopentadienyl)(tert-butyloxy)ruthenium(II)

Chemical Property of dicarbonyl(η5-pentaphenylcycopentadienyl)(tert-butyloxy)ruthenium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dicarbonyl(η5-pentaphenylcycopentadienyl)(tert-butyloxy)ruthenium(II)

There total 3 articles about dicarbonyl(η5-pentaphenylcycopentadienyl)(tert-butyloxy)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dicarbonyl(chloro)(η5-pentaphenylcyclopentadienyl)ruthenium(II) (677736-23-1) + potassium tert-butylate (865-47-4) → dicarbonyl(η5-pentaphenylcycopentadienyl)(tert-butyloxy)ruthenium(II) (860009-16-1)

Guidance literature:

In ⁽²⁾H₈-toluene; byproducts: KCl; mixt. shaken vigorously; not isolated; detd. by (13)C NMR;

DOI:10.1002/anie.200461416

Reference yield:

bromodicarbonyl(η-pentaphenylcyclopentadienyl)ruthenium + potassium tert-butylate (865-47-4) → dicarbonyl(η5-pentaphenylcycopentadienyl)(tert-butyloxy)ruthenium(II) (860009-16-1)

Guidance literature:

In toluene; Ru complex treated with 2 molar excess of t-BuOK; not isolated;

DOI:10.1021/ja051576x

Reference yield:

(η5-pentaphenylcyclopentadienylato)Ru(CO)2I (770729-72-1) + potassium tert-butylate (865-47-4) → dicarbonyl(η5-pentaphenylcycopentadienyl)(tert-butyloxy)ruthenium(II) (860009-16-1)

Guidance literature:

In toluene; Ru complex treated with 2 molar excess of t-BuOK; not isolated;

DOI:10.1021/ja051576x

upstream raw materials:

dicarbonyl(chloro)(η⁵-pentaphenylcyclopentadienyl)ruthenium(II)

potassium tert-butylate

(η5-pentaphenylcyclopentadienylato)Ru(CO)2I

Downstream raw materials:

(C₅(C₆H₅)5)Ru(CO)2(OCHCH₃C₆H₅)

carbonyl([13-C]carbonyl)(η5.pentaphenylcyclopentadienyl)(tert-butyloxy)ruthenium(II)

(η5-Ph5C5)Ru(CO)(C(O)OCH(Me)CH2CH2CHCH2)