Technology Process of 7,12-diphenylbenzo[k]fluoranthene-9-boronic acid
There total 4 articles about 7,12-diphenylbenzo[k]fluoranthene-9-boronic acid which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
9-bromo-7,12-diphenylbenzo[k]fluoranthene;
With
n-butyllithium;
In
tetrahydrofuran; hexane;
at -80 ℃;
for 0.666667h;
triethyl borate;
In
tetrahydrofuran; hexane;
for 2h;
With
hydrogenchloride; water;
In
tetrahydrofuran; hexane;
for 12h;
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: potassium hydroxide / ethanol / Reflux
2.1: isopentyl nitrite / dichloromethane / 13 h / Reflux
2.2: 12 h / Reflux
3.1: n-butyllithium / hexane; tetrahydrofuran / 0.67 h / -80 °C
3.2: 2 h
3.3: 12 h
With
n-butyllithium; potassium hydroxide; isopentyl nitrite;
In
tetrahydrofuran; ethanol; hexane; dichloromethane;
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: potassium hydroxide / ethanol / Reflux
2.1: isopentyl nitrite / dichloromethane / 13 h / Reflux
2.2: 12 h / Reflux
3.1: n-butyllithium / hexane; tetrahydrofuran / 0.67 h / -80 °C
3.2: 2 h
3.3: 12 h
With
n-butyllithium; potassium hydroxide; isopentyl nitrite;
In
tetrahydrofuran; ethanol; hexane; dichloromethane;
