4-(benzyloxy)-2-(4'-methylbenzenesulfonyl)-5-exo-nitro-3-oxo-2-azabicyclo<2.2.2>-7-octene

Base Information

Chemical Name:4-(benzyloxy)-2-(4'-methylbenzenesulfonyl)-5-exo-nitro-3-oxo-2-azabicyclo<2.2.2>-7-octene
CAS No.:141725-49-7
Molecular Formula:C₂₁H₂₀N₂O₆S
Molecular Weight:428.466
Hs Code.:

Synonyms:4-(benzyloxy)-2-(4'-methylbenzenesulfonyl)-5-exo-nitro-3-oxo-2-azabicyclo<2.2.2>-7-octene

Suppliers and Price of 4-(benzyloxy)-2-(4'-methylbenzenesulfonyl)-5-exo-nitro-3-oxo-2-azabicyclo<2.2.2>-7-octene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 4-(benzyloxy)-2-(4'-methylbenzenesulfonyl)-5-exo-nitro-3-oxo-2-azabicyclo<2.2.2>-7-octene

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 4-(benzyloxy)-2-(4'-methylbenzenesulfonyl)-5-exo-nitro-3-oxo-2-azabicyclo<2.2.2>-7-octene

There total 2 articles about 4-(benzyloxy)-2-(4'-methylbenzenesulfonyl)-5-exo-nitro-3-oxo-2-azabicyclo<2.2.2>-7-octene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 141667-39-2
4-(benzyloxy)-2-(4'-methylbenzenesulfonyl)-5-endo-nitro-3-oxo-2-azabicyclo<2.2.2>-7-octene

: 141725-49-7
4-(benzyloxy)-2-(4'-methylbenzenesulfonyl)-5-exo-nitro-3-oxo-2-azabicyclo<2.2.2>-7-octene

Guidance literature:: With ammonium formate; In methanol; dichloromethane; for 60h; Ambient temperature;
DOI:10.1021/jo00041a010

Reference yield:

: 141667-30-3
1-(4'-methylbenzenesulfonyl)-3-(phenylmethoxy)-2-pyridone

: 141725-49-7
4-(benzyloxy)-2-(4'-methylbenzenesulfonyl)-5-exo-nitro-3-oxo-2-azabicyclo<2.2.2>-7-octene

Guidance literature:: Multi-step reaction with 2 steps

1: 79 percent / CH₂Cl₂ / 120 h / 90 °C

2: 89 percent / ammonium formate / CH₂Cl₂; methanol / 60 h / Ambient temperature

With ammonium formate; In methanol; dichloromethane;
DOI:10.1021/jo00041a010