<(2,4,6-trideoxy-3-O-<(1,1-dimethylethyl)dimethylsilyl>-4-<(2,4-dinitrophenyl)thio>-β-D-ribo-hexopyranosyl)oxy><2-(trimethylsilyl)ethoxycarbonyl>amine

Base Information

Chemical Name:<(2,4,6-trideoxy-3-O-<(1,1-dimethylethyl)dimethylsilyl>-4-<(2,4-dinitrophenyl)thio>-β-D-ribo-hexopyranosyl)oxy><2-(trimethylsilyl)ethoxycarbonyl>amine
CAS No.:134262-74-1
Molecular Formula:C₂₄H₄₁N₃O₉SSi₂
Molecular Weight:603.841
Hs Code.:

<(2,4,6-trideoxy-3-O-<(1,1-dimethylethyl)dimethylsilyl>-4-<(2,4-dinitrophenyl)thio>-β-D-ribo-hexopyranosyl)oxy><2-(trimethylsilyl)ethoxycarbonyl>amine

Synonyms:<(2,4,6-trideoxy-3-O-<(1,1-dimethylethyl)dimethylsilyl>-4-<(2,4-dinitrophenyl)thio>-β-D-ribo-hexopyranosyl)oxy><2-(trimethylsilyl)ethoxycarbonyl>amine

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Chemical Property of <(2,4,6-trideoxy-3-O-<(1,1-dimethylethyl)dimethylsilyl>-4-<(2,4-dinitrophenyl)thio>-β-D-ribo-hexopyranosyl)oxy><2-(trimethylsilyl)ethoxycarbonyl>amine

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Technology Process of <(2,4,6-trideoxy-3-O-<(1,1-dimethylethyl)dimethylsilyl>-4-<(2,4-dinitrophenyl)thio>-β-D-ribo-hexopyranosyl)oxy><2-(trimethylsilyl)ethoxycarbonyl>amine

There total 14 articles about <(2,4,6-trideoxy-3-O-<(1,1-dimethylethyl)dimethylsilyl>-4-<(2,4-dinitrophenyl)thio>-β-D-ribo-hexopyranosyl)oxy><2-(trimethylsilyl)ethoxycarbonyl>amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

: 134262-94-5
N-<2-(trimethylsilyl)ethoxycarbonyl>hydroxylamine

: 134262-68-3
1,5-anhydro-2,4,6-trideoxy-3-O-<(1,1-dimethylethyl)dimethylsilyl>-4-<(2,4-dinitrophenyl)thio>-D-ribo-hex-1-enopyranose

: 134262-74-1
<(2,4,6-trideoxy-3-O-<(1,1-dimethylethyl)dimethylsilyl>-4-<(2,4-dinitrophenyl)thio>-β-D-ribo-hexopyranosyl)oxy><2-(trimethylsilyl)ethoxycarbonyl>amine

: C₂₄H₄₁N₃O₉SSi₂

Guidance literature:: With triphenylphosphine hydrobromide; In dichloromethane; Ambient temperature;
DOI:10.1021/ja00013a065

Reference yield:

: 69739-34-0
t-butyldimethylsiyl triflate

: 134262-74-1
<(2,4,6-trideoxy-3-O-<(1,1-dimethylethyl)dimethylsilyl>-4-<(2,4-dinitrophenyl)thio>-β-D-ribo-hexopyranosyl)oxy><2-(trimethylsilyl)ethoxycarbonyl>amine

Guidance literature:: Multi-step reaction with 2 steps

1: pyridine / CH₂Cl₂

2: Ph₃P-HBr / CH₂Cl₂

With pyridine; triphenylphosphine hydrobromide; In dichloromethane;
DOI:10.1021/jo951560x

Reference yield:

: 125848-19-3,286410-13-7
phenyl-2,4-di-O-acetyl-2,3-dideoxy-1-thio-α-D-threo-hex-2-eno-pyranoside

: 134262-74-1
<(2,4,6-trideoxy-3-O-<(1,1-dimethylethyl)dimethylsilyl>-4-<(2,4-dinitrophenyl)thio>-β-D-ribo-hexopyranosyl)oxy><2-(trimethylsilyl)ethoxycarbonyl>amine

Guidance literature:: Multi-step reaction with 8 steps

1: NaOMe / methanol

2: 86 percent / TBAB / CH₂Cl₂

3: 91 percent / LAH / tetrahydrofuran

4: 1.) MsCl, Et₃N / 2.) DMF

5: 1.) LAH / 1.) THF

6: 1.) m-CBA, 2.) Et₂NH / 1.) CH₂Cl₂, 2.) THF

7: pyridine / CH₂Cl₂

8: Ph₃P-HBr / CH₂Cl₂

With pyridine; lithium aluminium tetrahydride; m-formylphenyl benzoic acid; tetrabutylammomium bromide; sodium methylate; triphenylphosphine hydrobromide; methanesulfonyl chloride; diethylamine; triethylamine; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1021/jo951560x