cis-[Pt(CCCCH)2(1,3-bis(diphenylphosphino)propane)]

Base Information

Chemical Name:cis-[Pt(CCCCH)2(1,3-bis(diphenylphosphino)propane)]
CAS No.:431047-74-4
Molecular Formula:C₃₅H₂₈P₂Pt
Molecular Weight:705.635
Hs Code.:

Synonyms:cis-[Pt(CCCCH)2(1,3-bis(diphenylphosphino)propane)]

Suppliers and Price of cis-[Pt(CCCCH)2(1,3-bis(diphenylphosphino)propane)]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of cis-[Pt(CCCCH)2(1,3-bis(diphenylphosphino)propane)]

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of cis-[Pt(CCCCH)2(1,3-bis(diphenylphosphino)propane)]

There total 1 articles about cis-[Pt(CCCCH)2(1,3-bis(diphenylphosphino)propane)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 460-12-8,27987-87-7
Butadiyne

: 59329-00-9
[1,3-bis(diphenylphosphino)propane]dichloroplatinum(II)

: 431047-74-4
cis-[Pt(CCCCH)2(1,3-bis(diphenylphosphino)propane)]

Guidance literature:: With Et₂NH; copper(l) iodide; In tetrahydrofuran; (Ar); CuI was added to suspn. of Pt complex in THF/Et2NH; mixt. was maintained at 0°C; cold soln. of butadyine in THF was added; mixt. was stirred at 0°C for 2 h; solvent removed (vac.); residue dissolved in CH2Cl2; washed (H2O); org. phase dried (MgSO4); filtered; filtrate passed through alumina; solvent removed; crystd. (CH2Cl2/ether); dried (vac.); elem. anal.;
DOI:10.1021/om049690w

Reference yield: 78.0%

: 59329-00-9
[1,3-bis(diphenylphosphino)propane]dichloroplatinum(II)

: 431047-74-4
cis-[Pt(CCCCH)2(1,3-bis(diphenylphosphino)propane)]

: cyclo-[Pt(μ-CCCC)(1,3-bis(diphenylphosphino)propane)]4

Guidance literature:: With Et₂NH; copper(l) iodide; In tetrahydrofuran; (Ar); mixt. of Pt complexes in THF/Et2NH was stirred in presence of CuI at 55°C for 2 d; solvent removed (vac.); residue dissolved in CH2Cl2; washed (H2O); org. phase dried (MgSO4); filtered; filtrate passed through alumina; solvent removed; crystd. (CH2Cl2/ether); dried (vac.);
DOI:10.1021/om049690w

Reference yield: 73.0%

: 145332-53-2
(1,3-bis(diphenylphosphino)propane)bis(trifluoromethanesulfonato)platinum(II)

: 431047-74-4
cis-[Pt(CCCCH)2(1,3-bis(diphenylphosphino)propane)]

: cyclo-[Pt(μ-CCCC)(1,3-bis(diphenylphosphino)propane)]4

Guidance literature:: With NaOAc; In methanol; dichloromethane; byproducts: CF3SO3H; (N2); soln. of NaOAc in methanol was added to soln. of Pt-diynyl complexin CH2Cl2; Pt-triflate complex in CH2Cl2 was added over 2 h via syringe; solvent removed; hexane added; pptd.; elem. anal.;
DOI:10.1039/b107929h