(R)-benzyl 2-((5R,6R)-2,2,3,3,8,8,9,9-octamethyl-6-vinyl-4,7-dioxa-3,8-disiladecan-5-yl)aziridine-1-carboxylate

Base Information

Chemical Name:(R)-benzyl 2-((5R,6R)-2,2,3,3,8,8,9,9-octamethyl-6-vinyl-4,7-dioxa-3,8-disiladecan-5-yl)aziridine-1-carboxylate
CAS No.:1448794-42-0
Molecular Formula:C₂₆H₄₅NO₄Si₂
Molecular Weight:491.819
Hs Code.:

Synonyms:(R)-benzyl 2-((5R,6R)-2,2,3,3,8,8,9,9-octamethyl-6-vinyl-4,7-dioxa-3,8-disiladecan-5-yl)aziridine-1-carboxylate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (R)-benzyl 2-((5R,6R)-2,2,3,3,8,8,9,9-octamethyl-6-vinyl-4,7-dioxa-3,8-disiladecan-5-yl)aziridine-1-carboxylate

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Technology Process of (R)-benzyl 2-((5R,6R)-2,2,3,3,8,8,9,9-octamethyl-6-vinyl-4,7-dioxa-3,8-disiladecan-5-yl)aziridine-1-carboxylate

There total 6 articles about (R)-benzyl 2-((5R,6R)-2,2,3,3,8,8,9,9-octamethyl-6-vinyl-4,7-dioxa-3,8-disiladecan-5-yl)aziridine-1-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 1448794-41-9
(R)-2-((5R,6R)-2,2,3,3,8,8,9,9-octamethyl-6-vinyl-4,7-dioxa-3,8-disiladecan-5-yl)aziridine

: 501-53-1,94274-21-2
benzyl chloroformate

: 1448794-42-0
(R)-benzyl 2-((5R,6R)-2,2,3,3,8,8,9,9-octamethyl-6-vinyl-4,7-dioxa-3,8-disiladecan-5-yl)aziridine-1-carboxylate

Guidance literature:: With triethylamine; In dichloromethane; at 0 - 20 ℃; for 16h;
DOI:10.1039/c3ob40797g

Reference yield:

: 1448794-39-5
(5R,6R)-2,2,3,3,8,8,9,9-octamethyl-5-((S)-oxiran-2-yl)-6-vinyl-4,7-dioxa-3,8-disiladecane

: 1448794-42-0
(R)-benzyl 2-((5R,6R)-2,2,3,3,8,8,9,9-octamethyl-6-vinyl-4,7-dioxa-3,8-disiladecan-5-yl)aziridine-1-carboxylate

Guidance literature:: Multi-step reaction with 4 steps

1: lithium iodide; acetic acid / tetrahydrofuran / 6 h / 20 °C

2: sodium azide / N,N-dimethyl-formamide / 16 h / 40 °C

3: triphenylphosphine / toluene / 6 h / Reflux

4: triethylamine / dichloromethane / 16 h / 0 - 20 °C

With sodium azide; acetic acid; triethylamine; triphenylphosphine; lithium iodide; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; toluene;
DOI:10.1039/c3ob40797g

Reference yield:

: 132856-04-3,132956-65-1,132956-66-2,132956-67-3
(1S,2R)-1-((S)-oxiran-2-yl)but-3-ene-1,2-diol

: 1448794-42-0
(R)-benzyl 2-((5R,6R)-2,2,3,3,8,8,9,9-octamethyl-6-vinyl-4,7-dioxa-3,8-disiladecan-5-yl)aziridine-1-carboxylate

Guidance literature:: Multi-step reaction with 5 steps

1: 1H-imidazole / dichloromethane / 16 h / 0 °C / Reflux

2: lithium iodide; acetic acid / tetrahydrofuran / 6 h / 20 °C

3: sodium azide / N,N-dimethyl-formamide / 16 h / 40 °C

4: triphenylphosphine / toluene / 6 h / Reflux

5: triethylamine / dichloromethane / 16 h / 0 - 20 °C

With 1H-imidazole; sodium azide; acetic acid; triethylamine; triphenylphosphine; lithium iodide; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; toluene;
DOI:10.1039/c3ob40797g