trans-3-(tetra-O-benzoyl-α-D-glucopyranosyl)-1-(p-tolylsulfonyl)-1-propene

Base Information

• Chemical Name: trans-3-(tetra-O-benzoyl-α-D-glucopyranosyl)-1-(p-tolylsulfonyl)-1-propene
• CAS No.: 125365-12-0
• Molecular Formula: C₄₄H₃₈O₁₁S
• Molecular Weight: 774.845
• Mol file: 125365-12-0.mol

Synonyms:trans-3-(tetra-O-benzoyl-α-D-glucopyranosyl)-1-(p-tolylsulfonyl)-1-propene

Chemical Property of trans-3-(tetra-O-benzoyl-α-D-glucopyranosyl)-1-(p-tolylsulfonyl)-1-propene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-3-(tetra-O-benzoyl-α-D-glucopyranosyl)-1-(p-tolylsulfonyl)-1-propene

There total 3 articles about trans-3-(tetra-O-benzoyl-α-D-glucopyranosyl)-1-(p-tolylsulfonyl)-1-propene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

C50H44O11SSe → trans-3-(tetra-O-benzoyl-α-D-glucopyranosyl)-1-(p-tolylsulfonyl)-1-propene (125365-12-0)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; for 0.0833333h;

DOI:10.1016/0008-6215(89)85066-9

Reference yield:

p-tolyl benzeneselenosulfonate (68819-94-3) → trans-3-(tetra-O-benzoyl-α-D-glucopyranosyl)-1-(p-tolylsulfonyl)-1-propene (125365-12-0)

Guidance literature:

Multi-step reaction with 2 steps

1: 90 percent / CHCl₃ / 48 h / Heating

2: 99 percent / m-chloroperoxybenzoic acid / CH₂Cl₂ / 0.08 h

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; chloroform;

DOI:10.1016/0008-6215(89)85066-9

Reference yield:

3-(2',3',4',6'-tetra-O-benzoyl-α-D-glucopyranosyl)-1-propene (98854-01-4) → trans-3-(tetra-O-benzoyl-α-D-glucopyranosyl)-1-(p-tolylsulfonyl)-1-propene (125365-12-0)

Guidance literature:

Multi-step reaction with 2 steps

1: 90 percent / CHCl₃ / 48 h / Heating

2: 99 percent / m-chloroperoxybenzoic acid / CH₂Cl₂ / 0.08 h

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; chloroform;

DOI:10.1016/0008-6215(89)85066-9

upstream raw materials:

p-tolyl benzeneselenosulfonate

3-(2',3',4',6'-tetra-O-benzoyl-α-D-glucopyranosyl)-1-propene