Technology Process of C51H82O12SSi3
There total 14 articles about C51H82O12SSi3 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 7 steps
1: 92 percent / EtN(i-Pr)2, (Bu)4NI / CH2Cl2 / 32 h / Heating
2: 1.) LDA, 2.) mCPBA / 1.) THF, -78 deg C, 2.) hexane, 25 deg C, 5 h
3: 95 percent / CH2Cl2 / 15 h / -45 °C
4: 63 percent / Burgess' reagent
5: 80 percent / OsO4, pyridine / diethyl ether / 12 h / 0 °C
6: Et3N / -78 °C
7: LDA / 3 h / -35 °C
With
pyridine; osmium(VIII) oxide; Burgess Reagent; tetra-(n-butyl)ammonium iodide; triethylamine; N-ethyl-N,N-diisopropylamine; 3-chloro-benzenecarboperoxoic acid; lithium diisopropyl amide;
In
diethyl ether; dichloromethane;
- Guidance literature:
-
Multi-step reaction with 14 steps
1: O3
2: KMnO4, KH2PO4
4: 93 percent / LDA / tetrahydrofuran / 0.5 h / -78 °C
5: 100 percent / p-TsOH
6: 92 percent / PhSK / dimethylformamide / 3 h / 86 °C
7: acid
8: 92 percent / EtN(i-Pr)2, (Bu)4NI / CH2Cl2 / 32 h / Heating
9: 1.) LDA, 2.) mCPBA / 1.) THF, -78 deg C, 2.) hexane, 25 deg C, 5 h
10: 95 percent / CH2Cl2 / 15 h / -45 °C
11: 63 percent / Burgess' reagent
12: 80 percent / OsO4, pyridine / diethyl ether / 12 h / 0 °C
13: Et3N / -78 °C
14: LDA / 3 h / -35 °C
With
pyridine; potassium permanganate; potassium dihydrogenphosphate; osmium(VIII) oxide; Burgess Reagent; tetra-(n-butyl)ammonium iodide; (2E)-3-(4-hydroxyphenyl-3-methoxyphenyl)-1-phenylprop-2-en-1-one; toluene-4-sulfonic acid; ozone; triethylamine; N-ethyl-N,N-diisopropylamine; 3-chloro-benzenecarboperoxoic acid; lithium diisopropyl amide;
In
tetrahydrofuran; diethyl ether; dichloromethane; N,N-dimethyl-formamide;
- Guidance literature:
-
Multi-step reaction with 8 steps
1: acid
2: 92 percent / EtN(i-Pr)2, (Bu)4NI / CH2Cl2 / 32 h / Heating
3: 1.) LDA, 2.) mCPBA / 1.) THF, -78 deg C, 2.) hexane, 25 deg C, 5 h
4: 95 percent / CH2Cl2 / 15 h / -45 °C
5: 63 percent / Burgess' reagent
6: 80 percent / OsO4, pyridine / diethyl ether / 12 h / 0 °C
7: Et3N / -78 °C
8: LDA / 3 h / -35 °C
With
pyridine; osmium(VIII) oxide; Burgess Reagent; tetra-(n-butyl)ammonium iodide; triethylamine; N-ethyl-N,N-diisopropylamine; 3-chloro-benzenecarboperoxoic acid; lithium diisopropyl amide;
In
diethyl ether; dichloromethane;