1-[4-(3,6-di-tert-butyl-N-carbazolyl)phenyl]hexa-1,3,5-triyne

Base Information

• Chemical Name: 1-[4-(3,6-di-tert-butyl-N-carbazolyl)phenyl]hexa-1,3,5-triyne
• CAS No.: 1033351-51-7
• Molecular Formula: C₃₂H₂₉N
• Molecular Weight: 427.589
• Mol file: 1033351-51-7.mol

Synonyms:1-[4-(3,6-di-tert-butyl-N-carbazolyl)phenyl]hexa-1,3,5-triyne

Chemical Property of 1-[4-(3,6-di-tert-butyl-N-carbazolyl)phenyl]hexa-1,3,5-triyne

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of 1-[4-(3,6-di-tert-butyl-N-carbazolyl)phenyl]hexa-1,3,5-triyne

There total 1 articles about 1-[4-(3,6-di-tert-butyl-N-carbazolyl)phenyl]hexa-1,3,5-triyne which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

1-[4-(3,6-di-tert-butyl-N-carbazolyl)phenyl]-6-trimethylsilyl-1,3,5-hexatriyne (1033351-49-3) → 1-[4-(3,6-di-tert-butyl-N-carbazolyl)phenyl]hexa-1,3,5-triyne (1033351-51-7)

Guidance literature:

With methanol; potassium carbonate; In dichloromethane; at 20 ℃; for 1h;

DOI:10.1021/ol801121p

Reference yield: 65.0%

1-[4-(3,6-di-tert-butyl-N-carbazolyl)phenyl]hexa-1,3,5-triyne (1033351-51-7) → 1-[4-(3,6-di-tert-butyl-N-carbazolyl)phenyl]-6-iodo-1,3,5-hexatriyne (1033351-53-9)

Guidance literature:

With N-iodo-succinimide; silver nitrate; In acetone; at 20 ℃; for 1h;

DOI:10.1021/ol801121p

Reference yield: 10.0%

1-[4-(3,6-di-tert-butyl-N-carbazolyl)phenyl]hexa-1,3,5-triyne (1033351-51-7) + 1-trimethylsilyl-4-iodobuta-1,3-diyne (122223-21-6) → 1-[4-(3,6-di-tert-butyl-N-carbazolyl)phenyl]-10-trimethylsilyldeca-1,3,5,7,9-pentayne (1033351-55-1) + 1,12-bis[4-(3,6-di-tert-butyl-N-carbazolyl)phenyl]dodeca-1,3,5,7,9,11-hexyne (1033351-61-9)

Guidance literature:

With copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; triethylamine; at 20 ℃; for 12h; Inert atmosphere;

DOI:10.1021/ol801121p

upstream raw materials:

1-[4-(3,6-di-tert-butyl-N-carbazolyl)phenyl]-6-trimethylsilyl-1,3,5-hexatriyne

Downstream raw materials:

1-[4-(3,6-di-tert-butyl-N-carbazolyl)phenyl]-6-iodo-1,3,5-hexatriyne

1-[4-(3,6-di-tert-butyl-N-carbazolyl)phenyl]-10-trimethylsilyldeca-1,3,5,7,9-pentayne

1,12-bis[4-(3,6-di-tert-butyl-N-carbazolyl)phenyl]dodeca-1,3,5,7,9,11-hexyne