4R-(4α,5β,6β) 4-azido-5,6-bis<(4-methoxyphenyl)methoxy>-2-cyclohexen-1-one

Base Information

Chemical Name:4R-(4α,5β,6β) 4-azido-5,6-bis<(4-methoxyphenyl)methoxy>-2-cyclohexen-1-one
CAS No.:153165-82-3
Molecular Formula:C₂₂H₂₃N₃O₅
Molecular Weight:409.442
Hs Code.:

Synonyms:4R-(4α,5β,6β) 4-azido-5,6-bis<(4-methoxyphenyl)methoxy>-2-cyclohexen-1-one

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Chemical Property of 4R-(4α,5β,6β) 4-azido-5,6-bis<(4-methoxyphenyl)methoxy>-2-cyclohexen-1-one

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Technology Process of 4R-(4α,5β,6β) 4-azido-5,6-bis<(4-methoxyphenyl)methoxy>-2-cyclohexen-1-one

There total 6 articles about 4R-(4α,5β,6β) 4-azido-5,6-bis<(4-methoxyphenyl)methoxy>-2-cyclohexen-1-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 153165-81-2
2S-(2β,3β,4α,5α) 4-azido-5-hydroxy-2,3-bis<(4-methoxyphenyl)methoxy>-cyclohexanone

: 153165-82-3
4R-(4α,5β,6β) 4-azido-5,6-bis<(4-methoxyphenyl)methoxy>-2-cyclohexen-1-one

Guidance literature:: With pyridine; methanesulfonyl chloride; In dichloromethane;
DOI:10.1016/S0040-4020(01)87223-9

Reference yield:

: 116003-77-1
2-azido-2-deoxy-4,6-O-(phenylmethylene)methyl-α-D-altropyranoside

: 153165-82-3
4R-(4α,5β,6β) 4-azido-5,6-bis<(4-methoxyphenyl)methoxy>-2-cyclohexen-1-one

Guidance literature:: Multi-step reaction with 5 steps

1: 87 percent / NBS, CaCO₃ / CCl₄ / 80 °C

2: MeONa / methanol

3: NaH / dimethylformamide

4: 74 percent / Hg(CF₃CO₂)2 / acetone; H₂O / 20 °C

5: 60 percent / mesyl chloride, pyridine / CH₂Cl₂

With pyridine; N-Bromosuccinimide; Hg(II) trifluoroacetate; sodium methylate; sodium hydride; methanesulfonyl chloride; calcium carbonate; In methanol; tetrachloromethane; dichloromethane; water; N,N-dimethyl-formamide; acetone;
DOI:10.1016/S0040-4020(01)87223-9

Reference yield:

: 2746-25-0
p-Methoxybenzyl bromide

: 153165-82-3
4R-(4α,5β,6β) 4-azido-5,6-bis<(4-methoxyphenyl)methoxy>-2-cyclohexen-1-one

Guidance literature:: Multi-step reaction with 3 steps

1: NaH / dimethylformamide

2: 74 percent / Hg(CF₃CO₂)2 / acetone; H₂O / 20 °C

3: 60 percent / mesyl chloride, pyridine / CH₂Cl₂

With pyridine; Hg(II) trifluoroacetate; sodium hydride; methanesulfonyl chloride; In dichloromethane; water; N,N-dimethyl-formamide; acetone;
DOI:10.1016/S0040-4020(01)87223-9