phenyl 2-azido-3-O-benzyl-2-deoxy-4-O-p-methoxybenzyl-1-thio-6-O-trifluoroethylsulfonate-α-D-glucopyranoside

Base Information

Chemical Name:phenyl 2-azido-3-O-benzyl-2-deoxy-4-O-p-methoxybenzyl-1-thio-6-O-trifluoroethylsulfonate-α-D-glucopyranoside
CAS No.:763129-73-3
Molecular Formula:C₂₉H₃₀F₃N₃O₈S₂
Molecular Weight:669.7
Hs Code.:

Synonyms:phenyl 2-azido-3-O-benzyl-2-deoxy-4-O-p-methoxybenzyl-1-thio-6-O-trifluoroethylsulfonate-α-D-glucopyranoside

Suppliers and Price of phenyl 2-azido-3-O-benzyl-2-deoxy-4-O-p-methoxybenzyl-1-thio-6-O-trifluoroethylsulfonate-α-D-glucopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of phenyl 2-azido-3-O-benzyl-2-deoxy-4-O-p-methoxybenzyl-1-thio-6-O-trifluoroethylsulfonate-α-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of phenyl 2-azido-3-O-benzyl-2-deoxy-4-O-p-methoxybenzyl-1-thio-6-O-trifluoroethylsulfonate-α-D-glucopyranoside

There total 3 articles about phenyl 2-azido-3-O-benzyl-2-deoxy-4-O-p-methoxybenzyl-1-thio-6-O-trifluoroethylsulfonate-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 371-67-5
2,2,2-trifluorodiazoethane

: 763129-77-7
phenyl 2-azido-3-O-benzyl-2-deoxy-4-O-p-methoxybenzyl-1-thio-α-D-glucopyranoside

: 763129-73-3
phenyl 2-azido-3-O-benzyl-2-deoxy-4-O-p-methoxybenzyl-1-thio-6-O-trifluoroethylsulfonate-α-D-glucopyranoside

Guidance literature:: phenyl 2-azido-3-O-benzyl-2-deoxy-4-O-p-methoxybenzyl-1-thio-α-D-glucopyranoside; With triethylamine sulfurtrioxide; In N,N-dimethyl-formamide; at 50 ℃; for 4h;

2,2,2-trifluorodiazoethane; With citric acid; In acetonitrile; at 20 ℃; for 24h; Further stages.;
DOI:10.1016/j.tetlet.2004.06.131

Reference yield:

: 183875-22-1
phenyl 2-azido-2-deoxy-3,4,6-tri-O-acetyl-1-thio-α/β-D-glucopyranoside

: 763129-73-3
phenyl 2-azido-3-O-benzyl-2-deoxy-4-O-p-methoxybenzyl-1-thio-6-O-trifluoroethylsulfonate-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1.1: MeONa / methanol / 20 °C

1.2: 70 percent / camphorsulphonic acid; dimethylanisaldehyde acetal / acetonitrile / 1 h / 20 °C

2.1: NaH / dimethylformamide / 0.5 h / 0 °C

2.2: 80 percent / dimethylformamide / 0.67 h / 0 - 20 °C

3.1: 91 percent / BH₃*THF; diphenylborane triflate / CH₂Cl₂ / 0.67 h / 0 °C

4.1: Et₃N*SO₃ / dimethylformamide / 4 h / 50 °C

4.2: 70 percent / citric acid / acetonitrile / 24 h / 20 °C

With borane-THF; diphenylboryl triflate; sodium methylate; triethylamine sulfurtrioxide; sodium hydride; In methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/j.tetlet.2004.06.131

Reference yield:

: 819870-57-0
phenyl 2-azido-3-O-benzyl-2-deoxy-4,6-O-p-methoxybenzylidene-1-thio-α-D-glucopyranoside

: 763129-73-3
phenyl 2-azido-3-O-benzyl-2-deoxy-4-O-p-methoxybenzyl-1-thio-6-O-trifluoroethylsulfonate-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1.1: 91 percent / BH₃*THF; diphenylborane triflate / CH₂Cl₂ / 0.67 h / 0 °C

2.1: Et₃N*SO₃ / dimethylformamide / 4 h / 50 °C

2.2: 70 percent / citric acid / acetonitrile / 24 h / 20 °C

With borane-THF; diphenylboryl triflate; triethylamine sulfurtrioxide; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/j.tetlet.2004.06.131