Technology Process of C26H34O4
There total 5 articles about C26H34O4 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
C16H17BrO3;
With
n-butyllithium; N,N,N,N,-tetramethylethylenediamine;
In
hexanes; diethyl ether;
for 15h;
Inert atmosphere;
Cooling;
With
copper(l) iodide;
In
tetrahydrofuran; hexanes;
for 0.25h;
Inert atmosphere;
Cooling;
(R,E)-3-(5-bromo-3-methylpent-3-en-1-yl)-2,2-dimethyloxirane;
In
tetrahydrofuran; hexanes;
at 20 ℃;
Inert atmosphere;
Cooling;
DOI:10.1021/jo1022102
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: lithium borohydride / diethyl ether / 20.5 h / 0 °C / Inert atmosphere
2.1: sodium hydride / tetrahydrofuran; mineral oil / 0.17 h / 0 °C / Inert atmosphere
3.1: n-butyllithium; N,N,N,N,-tetramethylethylenediamine / hexanes; diethyl ether / 15 h / Inert atmosphere; Cooling
3.2: 0.25 h / Inert atmosphere; Cooling
3.3: 20 °C / Inert atmosphere; Cooling
With
lithium borohydride; n-butyllithium; N,N,N,N,-tetramethylethylenediamine; sodium hydride;
In
tetrahydrofuran; hexanes; diethyl ether; mineral oil;
DOI:10.1021/jo1022102
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: sodium hydride / tetrahydrofuran; mineral oil / 0.17 h / 0 °C / Inert atmosphere
2.1: n-butyllithium; N,N,N,N,-tetramethylethylenediamine / hexanes; diethyl ether / 15 h / Inert atmosphere; Cooling
2.2: 0.25 h / Inert atmosphere; Cooling
2.3: 20 °C / Inert atmosphere; Cooling
With
n-butyllithium; N,N,N,N,-tetramethylethylenediamine; sodium hydride;
In
tetrahydrofuran; hexanes; diethyl ether; mineral oil;
DOI:10.1021/jo1022102
