{2-[3,5-dibromo-4-(tert-butyl-dimethyl-silanyloxy)-phenyl]-ethyl}-carbamic acid tert-butyl ester

Base Information

Chemical Name:{2-[3,5-dibromo-4-(tert-butyl-dimethyl-silanyloxy)-phenyl]-ethyl}-carbamic acid tert-butyl ester
CAS No.:958255-21-5
Molecular Formula:C₁₉H₃₁Br₂NO₃Si
Molecular Weight:509.354
Hs Code.:

{2-[3,5-dibromo-4-(<i>tert</i>-butyl-dimethyl-silanyloxy)-phenyl]-ethyl}-carbamic acid <i>tert</i>-butyl ester

Synonyms:{2-[3,5-dibromo-4-(tert-butyl-dimethyl-silanyloxy)-phenyl]-ethyl}-carbamic acid tert-butyl ester

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Chemical Property of {2-[3,5-dibromo-4-(tert-butyl-dimethyl-silanyloxy)-phenyl]-ethyl}-carbamic acid tert-butyl ester

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Technology Process of {2-[3,5-dibromo-4-(tert-butyl-dimethyl-silanyloxy)-phenyl]-ethyl}-carbamic acid tert-butyl ester

There total 6 articles about {2-[3,5-dibromo-4-(tert-butyl-dimethyl-silanyloxy)-phenyl]-ethyl}-carbamic acid tert-butyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 958255-20-4
[4-(2-azido-ethyl)-2,6-dibromo-phenoxy]-tert-butyl-dimethyl-silane

: 24424-99-5
di-tert-butyl dicarbonate

: 958255-21-5
{2-[3,5-dibromo-4-(tert-butyl-dimethyl-silanyloxy)-phenyl]-ethyl}-carbamic acid tert-butyl ester

Guidance literature:: [4-(2-azido-ethyl)-2,6-dibromo-phenoxy]-tert-butyl-dimethyl-silane; With triphenylphosphine; In methanol; at 20 ℃; for 4h;

di-tert-butyl dicarbonate; In methanol; for 4h;

Reference yield:

: 958255-19-1
2-[3,5-dibromo-4-(tert-butyl-dimethyl-silanyloxy)-phenyl]-ethanol

: 958255-21-5
{2-[3,5-dibromo-4-(tert-butyl-dimethyl-silanyloxy)-phenyl]-ethyl}-carbamic acid tert-butyl ester

Guidance literature:: Multi-step reaction with 3 steps

1.1: 82 percent / triethylamine / CH₂Cl₂ / 3 h / cooling

2.1: 86 percent / sodium azide / dimethylformamide / 4 h / Heating

3.1: triphenylphosphine / methanol / 4 h / 20 °C

3.2: 85 percent / methanol / 4 h

With sodium azide; triethylamine; triphenylphosphine; In methanol; dichloromethane; N,N-dimethyl-formamide;

Reference yield:

: 958255-18-0
3,5-dibromo-4-{[tert-butyl(dimethyl)silyl]oxy}phenylacetic acid methyl ester

: 958255-21-5
{2-[3,5-dibromo-4-(tert-butyl-dimethyl-silanyloxy)-phenyl]-ethyl}-carbamic acid tert-butyl ester

Guidance literature:: Multi-step reaction with 4 steps

1.1: 76 percent / lithium aluminium hydride / tetrahydrofuran / 12 h / 20 °C

2.1: 82 percent / triethylamine / CH₂Cl₂ / 3 h / cooling

3.1: 86 percent / sodium azide / dimethylformamide / 4 h / Heating

4.1: triphenylphosphine / methanol / 4 h / 20 °C

4.2: 85 percent / methanol / 4 h

With lithium aluminium tetrahydride; sodium azide; triethylamine; triphenylphosphine; In tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide;