phenyl(2,4,6-triisopropylphenyl)iodonium trifluoromethanesulfonate

Base Information

• Chemical Name: phenyl(2,4,6-triisopropylphenyl)iodonium trifluoromethanesulfonate
• CAS No.: 312727-69-8
• Molecular Formula: CF₃O₃S*C₂₁H₂₈I
• Molecular Weight: 556.428
• Mol file: 312727-69-8.mol

Synonyms:phenyl(2,4,6-triisopropylphenyl)iodonium trifluoromethanesulfonate

Chemical Property of phenyl(2,4,6-triisopropylphenyl)iodonium trifluoromethanesulfonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of phenyl(2,4,6-triisopropylphenyl)iodonium trifluoromethanesulfonate

There total 3 articles about phenyl(2,4,6-triisopropylphenyl)iodonium trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

iodobenzene (591-50-4) + trifluorormethanesulfonic acid (1493-13-6) + 1,3,5-triisopropyl benzene (717-74-8) → phenyl(2,4,6-triisopropylphenyl)iodonium trifluoromethanesulfonate (312727-69-8)

Guidance literature:

iodobenzene; 1,3,5-triisopropyl benzene; With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 20 ℃; for 2h;

trifluorormethanesulfonic acid; In dichloromethane; at 0 - 20 ℃; for 2h;

DOI:10.1002/anie.201309305

Reference yield: 59.0%

trifluorormethanesulfonic acid (1493-13-6) + 1-iodo-2,4,6-triisopropylbenzene (2100-22-3) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → phenyl(2,4,6-triisopropylphenyl)iodonium trifluoromethanesulfonate (312727-69-8)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 20 ℃; for 16h; Sealed tube;

DOI:10.1002/anie.201603175

Reference yield:

iodobenzene (591-50-4) + trifluorormethanesulfonic acid (1493-13-6) + 1,3,5-trimethyl-benzene (108-67-8) → phenyl(2,4,6-triisopropylphenyl)iodonium trifluoromethanesulfonate (312727-69-8)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 0 - 20 ℃; for 17h;

DOI:10.1039/c5cc04944j

upstream raw materials:

iodobenzene

trifluorormethanesulfonic acid

1,3,5-triisopropyl benzene

1,3,5-trimethyl-benzene

Downstream raw materials:

methyldiphenylsilane

1-iodo-2,4,6-triisopropylbenzene

2,4,6-triisopropylphenyl 2-methylpentanoate

2,4,6-triisopropylphenyl 2,4,6-trimethylbenzoate

Refernces

• 1、 Pérez, Juana M.,Cano, Rafael,McGlacken, Gerard P.,Ramón, Diego J.. "Palladium(II) oxide impregnated on magnetite as a catalyst for the synthesis of 4-arylcoumarins: Via a Heck-arylation/cyclization process". . p. 36932 - 36941. Retrieved 2016/05/24.
• 2、 Tinnis, Fredrik,Stridfeldt, Elin,Lundberg, Helena,Adolfsson, Hans,Olofsson, Berit. "Metal-free n -arylation of secondary amides at room temperature". supporting information. p. 2688 - 2691. Retrieved 2015/06/16.