2,6,6-Trimethyl-2-cyclohexen-1-acetaldehyde

Base Information

Chemical Name:2,6,6-Trimethyl-2-cyclohexen-1-acetaldehyde
CAS No.:472-64-0
Deprecated CAS:165657-71-6
Molecular Formula:C11H18 O
Molecular Weight:166.263
Hs Code.:
European Community (EC) Number:207-453-5
DSSTox Substance ID:DTXSID50275968,DTXSID90883389
Nikkaji Number:J196.190J
Mol file:472-64-0.mol

Synonyms:2,6,6-Trimethyl-2-cyclohexen-1-acetaldehyde;472-64-0;2,6,6-Trimethyl-2-cyclohexene-1-acetaldehyde;EINECS 207-453-5;2-Cyclohexene-1-acetaldehyde, 2,6,6-trimethyl-;SCHEMBL1305568;DTXSID50275968;DTXSID90883389;2,6,6 - trimethyl - 2 - cyclohexene - 1 - acetaldehyde;165657-71-6

Suppliers and Price of 2,6,6-Trimethyl-2-cyclohexen-1-acetaldehyde

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 7 raw suppliers

Chemical Property of 2,6,6-Trimethyl-2-cyclohexen-1-acetaldehyde

Chemical Property:

Vapor Pressure:0.0915mmHg at 25°C
Boiling Point:224.4°Cat760mmHg
Flash Point:86.5°C
PSA：17.07000
Density:0.87g/cm³
LogP:2.95790
XLogP3:2.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:2
Exact Mass:166.135765193
Heavy Atom Count:12
Complexity:201

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CCCC(C1CC=O)(C)C

Technology Process of 2,6,6-Trimethyl-2-cyclohexen-1-acetaldehyde

There total 7 articles about 2,6,6-Trimethyl-2-cyclohexen-1-acetaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.5%

: 57576-14-4
(2,6,6-Trimethyl-2-cyclohexenyl)acetonitrile

: 472-64-0
(2,6,6-Trimethyl-2-cyclohexenyl)acetaldehyde

Guidance literature:: With diisobutylaluminium hydride; In hexane; for 3h; Ambient temperature;
DOI:10.1021/jo00117a005

Reference yield:

: 13395-71-6
2,4,4-trimethyl-2-cyclohexenone

: 472-64-0
(2,6,6-Trimethyl-2-cyclohexenyl)acetaldehyde

Guidance literature:: Multi-step reaction with 3 steps

1: (reduction)

2: Hg(OAc)2

3: 180 - 190 °C

With mercury(II) diacetate;

Reference yield:

: 20633-35-6
4-[1,3]dioxolan-2-yl-4-methyl-pentanenitrile

: 472-64-0
(2,6,6-Trimethyl-2-cyclohexenyl)acetaldehyde

Guidance literature:: Multi-step reaction with 4 steps

1: (i), (ii) aq. H₂SO₄

2: lithium aluminium tetrahydride / diethyl ether

3: mercury(II) diacetate / methanol

4: Heating

With lithium aluminium tetrahydride; mercury(II) diacetate; In methanol; diethyl ether;