(2S,3S,5R)-5-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-2-hexyl-hexadecanal

Base Information

Chemical Name:(2S,3S,5R)-5-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-2-hexyl-hexadecanal
CAS No.:1026575-03-0
Molecular Formula:C₃₅H₆₄O₃Si
Molecular Weight:560.977
Hs Code.:

Synonyms:(2S,3S,5R)-5-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-2-hexyl-hexadecanal

Suppliers and Price of (2S,3S,5R)-5-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-2-hexyl-hexadecanal

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2S,3S,5R)-5-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-2-hexyl-hexadecanal

Chemical Property:

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Technology Process of (2S,3S,5R)-5-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-2-hexyl-hexadecanal

There total 2 articles about (2S,3S,5R)-5-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-2-hexyl-hexadecanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (6R)-6-(Benzyloxy)-3-hexyl-4-hydroxy-1-heptadecene

: 1026575-03-0
(2S,3S,5R)-5-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-2-hexyl-hexadecanal

Guidance literature:: Multi-step reaction with 2 steps

1: imidazole, DMAP / dimethylformamide / 20 h / 55 °C

2: 1.) O₃, 2.) Me₂S, Et₃N / 1.) MeOH, CH₂Cl₂, -78 deg C, 4.5 h, 2.) room temp., 1 h

With 1H-imidazole; dmap; dimethylsulfide; ozone; triethylamine; In N,N-dimethyl-formamide;
DOI:10.1021/jo00079a022

Reference yield:

: (3R,4S,6R)-6-(Benzyloxy)-4-<(tert-butyldimethylsilyl)oxy>-3-hexyl-1-heptadecene

: 1026575-03-0
(2S,3S,5R)-5-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-2-hexyl-hexadecanal

Guidance literature:: With dimethylsulfide; ozone; triethylamine; Multistep reaction; 1.) MeOH, CH₂Cl₂, -78 deg C, 4.5 h, 2.) room temp., 1 h;
DOI:10.1021/jo00079a022

Reference yield:

: 1026575-03-0
(2S,3S,5R)-5-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-2-hexyl-hexadecanal

: 68711-40-0,104871-99-0,104872-00-6,104872-03-9,104872-05-1,104872-07-3,104872-19-7,104872-06-2
(3S,4S)-3-hexyl-4-[(R)-2-hydroxytridecyl]-2-oxetanone

Guidance literature:: Multi-step reaction with 4 steps

1: NaClO₂, NaH₂PO₄*H₂O / various solvent(s); 2-methyl-propan-2-ol; H₂O / 1.) 0 deg C, 3 h, 2.) room temp., 30 min

2: 48percent HF / acetonitrile / 5 h / Ambient temperature

3: benzenesulfonyl chloride, pyridine / 0 °C

4: H₂ / 10percent Pd-C / ethyl acetate

With pyridine; sodium chlorite; sodium dihydrogenphosphate; hydrogen fluoride; hydrogen; benzenesulfonyl chloride; palladium on activated charcoal; In water; ethyl acetate; acetonitrile; tert-butyl alcohol;
DOI:10.1021/jo00079a022