methyl 4,6-O-cyclohexylidene-2,3-dideoxy-2-p-toluenesulfonamido-α-D-ribohexopyranoside

Base Information

Chemical Name:methyl 4,6-O-cyclohexylidene-2,3-dideoxy-2-p-toluenesulfonamido-α-D-ribohexopyranoside
CAS No.:78151-16-3
Molecular Formula:C₂₀H₂₉NO₆S
Molecular Weight:411.519
Hs Code.:

Synonyms:methyl 4,6-O-cyclohexylidene-2,3-dideoxy-2-p-toluenesulfonamido-α-D-ribohexopyranoside

Suppliers and Price of methyl 4,6-O-cyclohexylidene-2,3-dideoxy-2-p-toluenesulfonamido-α-D-ribohexopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl 4,6-O-cyclohexylidene-2,3-dideoxy-2-p-toluenesulfonamido-α-D-ribohexopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl 4,6-O-cyclohexylidene-2,3-dideoxy-2-p-toluenesulfonamido-α-D-ribohexopyranoside

There total 10 articles about methyl 4,6-O-cyclohexylidene-2,3-dideoxy-2-p-toluenesulfonamido-α-D-ribohexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 78138-73-5
methyl 3-chloro-4,6-O-cyclohexylidene-2,3-dideoxy-2-p-toluenesulfonamido-α-D-glucopyranoside

: 78151-16-3
methyl 4,6-O-cyclohexylidene-2,3-dideoxy-2-p-toluenesulfonamido-α-D-ribohexopyranoside

Guidance literature:: With azobisisobutyronitrile; tri-n-butyl-tin hydride; In 1,4-dioxane; at 80 ℃; 1.) 1.5 h; 2.) 6.5 h;
DOI:10.1016/S0008-6215(00)85251-9

Reference yield: 73.0%

: 78138-71-3
methyl 4,6-O-cyclohexylidene-2,3-dideoxy-3-iodo-2-p-toluenesulfonamido-α-D-glucopyranoside

: 78151-16-3
methyl 4,6-O-cyclohexylidene-2,3-dideoxy-2-p-toluenesulfonamido-α-D-ribohexopyranoside

Guidance literature:: With azobisisobutyronitrile; tri-n-butyl-tin hydride; In 1,4-dioxane; at 80 ℃; for 1h;
DOI:10.1016/S0008-6215(00)85251-9

Reference yield:

: 69477-57-2
methyl 4,6-O-cyclohexylidene-2-deoxy-2-(methoxycarbonyl)amino-α-D-glucopyranoside

: 78151-16-3
methyl 4,6-O-cyclohexylidene-2,3-dideoxy-2-p-toluenesulfonamido-α-D-ribohexopyranoside

Guidance literature:: Multi-step reaction with 5 steps

1: 68 percent / 1.2 M aq. NaOH / dioxane / 6 h / 100 °C

2: 97 percent / anhydrous Na₂CO₃ / H₂O; dioxane / 3.5 h / 5 °C

3: 87 percent / pyridine / 0 °C

4: 94 percent / NaI / dimethylformamide / 5 h / 100 °C

5: 73 percent / tributylstannane, α,α'-azobisisobutyronitrile / dioxane / 1 h / 80 °C

With sodium hydroxide; azobisisobutyronitrile; tri-n-butyl-tin hydride; sodium carbonate; sodium iodide; In 1,4-dioxane; pyridine; water; N,N-dimethyl-formamide;
DOI:10.1016/S0008-6215(00)85251-9