3-[(1E)-7-hydroxy-3-methylocta-1,3-dienyl]-2,4,4-trimethylcyclohex-2-enol

Base Information

Chemical Name:3-[(1E)-7-hydroxy-3-methylocta-1,3-dienyl]-2,4,4-trimethylcyclohex-2-enol
CAS No.:929626-35-7
Molecular Formula:C₁₈H₃₀O₂
Molecular Weight:278.435
Hs Code.:

Synonyms:3-[(1E)-7-hydroxy-3-methylocta-1,3-dienyl]-2,4,4-trimethylcyclohex-2-enol

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Chemical Property of 3-[(1E)-7-hydroxy-3-methylocta-1,3-dienyl]-2,4,4-trimethylcyclohex-2-enol

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Technology Process of 3-[(1E)-7-hydroxy-3-methylocta-1,3-dienyl]-2,4,4-trimethylcyclohex-2-enol

There total 5 articles about 3-[(1E)-7-hydroxy-3-methylocta-1,3-dienyl]-2,4,4-trimethylcyclohex-2-enol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 3-[7-(tert-butyl-dimethyl-silanyloxy)-3-methyl-octa-1,3-dienyl]-2,4,4-trimethyl-cyclohex-2-enol

: 929626-35-7
3-[(1E)-7-hydroxy-3-methylocta-1,3-dienyl]-2,4,4-trimethylcyclohex-2-enol

Guidance literature:: With hydrogen fluoride; In water; acetonitrile; at 20 ℃; for 12h;
DOI:10.1021/jo062236c

Reference yield:

: 79-77-6,14901-07-6
(E)-β-ionone

: 929626-35-7
3-[(1E)-7-hydroxy-3-methylocta-1,3-dienyl]-2,4,4-trimethylcyclohex-2-enol

Guidance literature:: Multi-step reaction with 5 steps

1.1: 85 percent / 1,4-benzoquinone; o-methoxyacetophenone / palladium(II) trifluoroacetate / 12 h / 70 °C

2.1: LiN(SiMe₃)2 / tetrahydrofuran / 1 h / -78 - 0 °C

2.2: tetrahydrofuran / -78 - 20 °C

3.1: KOH / methanol / 6 h / 20 °C

4.1: Zn; I₂; DMAP / 3 h / 40 °C

4.2: Pd[PPh₃]4 / tetrahydrofuran / 49 h / -78 - 20 °C

5.1: 140 mg / HF / acetonitrile; H₂O / 12 h / 20 °C

With 2-Methoxyacetophenone; dmap; potassium hydroxide; hydrogen fluoride; iodine; p-benzoquinone; lithium hexamethyldisilazane; zinc; palladium(II) trifluoroacetate; In tetrahydrofuran; methanol; water; acetonitrile; 2.2: Wittig olefination;
DOI:10.1021/jo062236c

Reference yield:

: 929626-29-9
3-(4-bromo-3-methyl-buta-1,3-dienyl)-2,4,4-trimethyl-cyclohex-2-enol

: 929626-35-7
3-[(1E)-7-hydroxy-3-methylocta-1,3-dienyl]-2,4,4-trimethylcyclohex-2-enol

Guidance literature:: Multi-step reaction with 2 steps

1.1: Zn; I₂; DMAP / 3 h / 40 °C

1.2: Pd[PPh₃]4 / tetrahydrofuran / 49 h / -78 - 20 °C

2.1: 140 mg / HF / acetonitrile; H₂O / 12 h / 20 °C

With dmap; hydrogen fluoride; iodine; zinc; In water; acetonitrile;
DOI:10.1021/jo062236c