S-(p-toluyl) 4-O-(dimethyl-t-butyl silyl)-2-deoxy-3,6-di-O-benzoyl-2-phthalimido-1-thio-β-D-glucopyraoside

Base Information

Chemical Name:S-(p-toluyl) 4-O-(dimethyl-t-butyl silyl)-2-deoxy-3,6-di-O-benzoyl-2-phthalimido-1-thio-β-D-glucopyraoside
CAS No.:916902-01-7
Molecular Formula:C₄₁H₄₃NO₈SSi
Molecular Weight:737.946
Hs Code.:

Synonyms:S-(p-toluyl) 4-O-(dimethyl-t-butyl silyl)-2-deoxy-3,6-di-O-benzoyl-2-phthalimido-1-thio-β-D-glucopyraoside

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Chemical Property of S-(p-toluyl) 4-O-(dimethyl-t-butyl silyl)-2-deoxy-3,6-di-O-benzoyl-2-phthalimido-1-thio-β-D-glucopyraoside

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Technology Process of S-(p-toluyl) 4-O-(dimethyl-t-butyl silyl)-2-deoxy-3,6-di-O-benzoyl-2-phthalimido-1-thio-β-D-glucopyraoside

There total 10 articles about S-(p-toluyl) 4-O-(dimethyl-t-butyl silyl)-2-deoxy-3,6-di-O-benzoyl-2-phthalimido-1-thio-β-D-glucopyraoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 69739-34-0
t-butyldimethylsiyl triflate

: 220645-06-7
p-methylphenyl 3,6-di-O-benzoyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside

: 916902-01-7
S-(p-toluyl) 4-O-(dimethyl-t-butyl silyl)-2-deoxy-3,6-di-O-benzoyl-2-phthalimido-1-thio-β-D-glucopyraoside

Guidance literature:: With 2,4,6-trimethyl-pyridine; In dichloromethane; for 0.833333h;

Reference yield:

: 85-44-9
phthalic anhydride

: 916902-01-7
S-(p-toluyl) 4-O-(dimethyl-t-butyl silyl)-2-deoxy-3,6-di-O-benzoyl-2-phthalimido-1-thio-β-D-glucopyraoside

Guidance literature:: Multi-step reaction with 6 steps

1.1: sodium hydroxide / methanol; water / 0.25 h / Large scale

1.2: Large scale

2.1: pyridine; dmap / 48 h / 20 °C / Inert atmosphere; Large scale

3.1: boron trifluoride diethyl etherate / dichloromethane

4.1: sodium methylate / methanol / 20 °C

5.1: pyridine; dmap / dichloromethane / 19 h / 20 °C / Inert atmosphere; Cooling with ice

6.1: collidine / dichloromethane

With pyridine; dmap; boron trifluoride diethyl etherate; sodium methylate; sodium hydroxide; In methanol; dichloromethane; water;

Reference yield:

: 172847-90-4
p-methylphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside

: 916902-01-7
S-(p-toluyl) 4-O-(dimethyl-t-butyl silyl)-2-deoxy-3,6-di-O-benzoyl-2-phthalimido-1-thio-β-D-glucopyraoside

Guidance literature:: Multi-step reaction with 3 steps

1: sodium methylate / methanol / 20 °C

2: pyridine; dmap / dichloromethane / 19 h / 20 °C / Inert atmosphere; Cooling with ice

3: collidine / dichloromethane

With pyridine; dmap; sodium methylate; In methanol; dichloromethane;