methyl (3,4,6-tri-O-benzyl-2-deoxy-α-D-glucopyranosyl)-(1→3)-2-O-benzyl-4,6-O-benzylidine-α-D-glucopyranoside

Base Information

Chemical Name:methyl (3,4,6-tri-O-benzyl-2-deoxy-α-D-glucopyranosyl)-(1→3)-2-O-benzyl-4,6-O-benzylidine-α-D-glucopyranoside
CAS No.:1309355-92-7
Molecular Formula:C₄₈H₅₂O₁₀
Molecular Weight:788.935
Hs Code.:

Synonyms:methyl (3,4,6-tri-O-benzyl-2-deoxy-α-D-glucopyranosyl)-(1→3)-2-O-benzyl-4,6-O-benzylidine-α-D-glucopyranoside

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Chemical Property of methyl (3,4,6-tri-O-benzyl-2-deoxy-α-D-glucopyranosyl)-(1→3)-2-O-benzyl-4,6-O-benzylidine-α-D-glucopyranoside

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Technology Process of methyl (3,4,6-tri-O-benzyl-2-deoxy-α-D-glucopyranosyl)-(1→3)-2-O-benzyl-4,6-O-benzylidine-α-D-glucopyranoside

There total 9 articles about methyl (3,4,6-tri-O-benzyl-2-deoxy-α-D-glucopyranosyl)-(1→3)-2-O-benzyl-4,6-O-benzylidine-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 76375-66-1
methyl 2-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside

: 220284-26-4
3,4,6-Tri-O-benzyl-2-deoxy-α-D-glucopyranosyl trichloroacetamidate

: 1309355-92-7
methyl (3,4,6-tri-O-benzyl-2-deoxy-α-D-glucopyranosyl)-(1→3)-2-O-benzyl-4,6-O-benzylidine-α-D-glucopyranoside

Guidance literature:: With iron(III) chloride; In dichloromethane; at -60 - 20 ℃; for 0.666667h; Inert atmosphere; Molecular sieve;
DOI:10.1039/c6ra21859h

Reference yield: 66.0%

: p-methylphenyl 3,4,6-tri-O-benzyl-2-deoxy-1-thio-D-glucopyranoside

: 76375-66-1
methyl 2-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside

: 1309355-92-7
methyl (3,4,6-tri-O-benzyl-2-deoxy-α-D-glucopyranosyl)-(1→3)-2-O-benzyl-4,6-O-benzylidine-α-D-glucopyranoside

Guidance literature:: p-methylphenyl 3,4,6-tri-O-benzyl-2-deoxy-1-thio-D-glucopyranoside; With silver trifluoromethanesulfonate; p-toluenesulfonyl chloride; In dichloromethane; at -78 ℃; for 0.25h; Inert atmosphere; Molecular sieve;

methyl 2-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside; In dichloromethane; at -78 ℃; diastereoselective reaction; Inert atmosphere; Molecular sieve;
DOI:10.1002/chem.201203418

Reference yield:

: 119070-22-3
phenyl 2-deoxy-3,4,6-tris-O-(phenylmethyl)-1-thio-D-arabino-hexopyranoside

: 76375-66-1
methyl 2-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside

: 1309355-92-7
methyl (3,4,6-tri-O-benzyl-2-deoxy-α-D-glucopyranosyl)-(1→3)-2-O-benzyl-4,6-O-benzylidine-α-D-glucopyranoside

: 885375-13-3
methyl (3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranosyl)-(1→3)-2-O-benzyl-4,6-O-benzylidine-α-D-glucopyranoside

Guidance literature:: With 2,4,6-tri-tert-butylpyrimidine; trifluoroethyl phenyliodonium bis((trifluoromethyl)sulfonyl)imide; In dichloromethane; at 20 ℃; for 2.5h; Overall yield = 90%Chromat.; Inert atmosphere;