Junenol

Base Information

Chemical Name:Junenol
CAS No.:472-07-1
Molecular Formula:C15H26O
Molecular Weight:222.37
Hs Code.:
UNII:Z3209PC5TC
DSSTox Substance ID:DTXSID60963763
Nikkaji Number:J1.575.029D,J11.977F
Wikidata:Q27294925
Mol file:472-07-1.mol

Synonyms:Junenol;(+)-Junenol;472-07-1;UNII-Z3209PC5TC;Eudesm-4(14)-en-6alpha-ol;Z3209PC5TC;1-Naphthalenol, decahydro-4a-methyl-8-methylene-2-(1-methylethyl)-, (1S,2S,4aR,8aS)-;(1S-(1alpha,2beta,4abeta,8aalpha))-Decahydro-4a-methyl-8-methylene-2-(1-methylethyl)-1-naphthalenol;(1S,2S,4aR,8aS)-2-Isopropyl-4a-methyl-8-methylenedecahydronaphthalen-1-ol;1-Naphthalenol, decahydro-4a-methyl-8-methylene-2-(1-methylethyl)-, (1S-(1alpha,2beta,4abeta,8aalpha))-;Eudesm-4(14)-en-6.alpha.-ol;( )-Junenol;(1S,2S,4aR,8aS)-4a-methyl-8-methylidene-2-propan-2-yl-1,2,3,4,5,6,7,8a-octahydronaphthalen-1-ol;DTXSID60963763;1-NAPHTHALENOL, DECAHYDRO-4A-METHYL-8-METHYLENE-2-(1-METHYLETHYL)-, (1S-(1.ALPHA.,2.BETA.,4A.BETA.,8A.ALPHA.))-;AKOS040749865;Q27294925;4a-Methyl-8-methylidene-2-(propan-2-yl)decahydronaphthalen-1-ol;(8abeta)-Decahydro-8-methylene-4aalpha-methyl-2alpha-(1-methylethyl)naphthalene-1beta-ol

Suppliers and Price of Junenol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of Junenol

Chemical Property:

Vapor Pressure:8.6E-05mmHg at 25°C
Melting Point:62.5-63 °C
Boiling Point:304°C at 760 mmHg
PKA:14.98±0.60(Predicted)
Flash Point:128.5°C
PSA：20.23000
Density:0.95g/cm³
LogP:3.77590
XLogP3:4.2
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:222.198365449
Heavy Atom Count:16
Complexity:281

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)C1CCC2(CCCC(=C)C2C1O)C
Isomeric SMILES:CC(C)[C@@H]1CC[C@]2(CCCC(=C)[C@@H]2[C@H]1O)C

Technology Process of Junenol

There total 44 articles about Junenol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 28.0%

: (+/-)-acolamone

: 472-07-1,30951-17-8,38108-86-0,62358-38-7,66574-25-2,67597-12-0,75109-68-1,82795-50-4,94373-05-4
(+/-)-junenol

Guidance literature:: With sodium tetrahydroborate;

Reference yield:

: 1078-93-9,57963-81-2,74383-86-1
4,4,10-trimethyl-6-keto-trans-decalin

: 472-07-1,30951-17-8,38108-86-0,62358-38-7,66574-25-2,67597-12-0,75109-68-1,82795-50-4,94373-05-4
(+/-)-junenol

Guidance literature:: Multi-step reaction with 10 steps

1: 68 percent / NaH / 1,2-dimethoxy-ethane / 2 h / 80 - 85 °C

2: 72 percent / diethyl ether

3: 3 percent / HCl / methanol / 2 h / Heating

4: 28 mg / H₂ / Pd/C / methanol / 0.33 h / 6080 Torr

5: 80 percent / Na, EtOH / 100 - 110 °C

6: 65 percent / Pb(OAc)4, CaCO₃, I₂ / cyclohexane / 1.5 h / Heating; Irradiation

7: 48 percent / CrO₃, AcOH / 60 h / Ambient temperature

8: 15 percent / Jones' reagent / acetone / 6 h / Ambient temperature

9: 17 percent / Pb(OAc)4 / benzene; pyridine / 1.) room temperature, 1 h, 2.) reflux, 3 h

10: 6 mg / NaBH₄ / ethanol / 10 h

With chromium(VI) oxide; lead(IV) acetate; hydrogenchloride; sodium tetrahydroborate; jones' reagent; ethanol; hydrogen; iodine; sodium; sodium hydride; acetic acid; calcium carbonate; palladium on activated charcoal; In pyridine; methanol; 1,2-dimethoxyethane; diethyl ether; ethanol; cyclohexane; acetone; benzene;

Reference yield:

: (4aR,8aS)-2-(1-Hydroxy-1-methyl-ethyl)-4a,8,8-trimethyl-octahydro-naphthalen-1-one

: 472-07-1,30951-17-8,38108-86-0,62358-38-7,66574-25-2,67597-12-0,75109-68-1,82795-50-4,94373-05-4
(+/-)-junenol

Guidance literature:: Multi-step reaction with 8 steps

1: 3 percent / HCl / methanol / 2 h / Heating

2: 28 mg / H₂ / Pd/C / methanol / 0.33 h / 6080 Torr

3: 80 percent / Na, EtOH / 100 - 110 °C

4: 65 percent / Pb(OAc)4, CaCO₃, I₂ / cyclohexane / 1.5 h / Heating; Irradiation

5: 48 percent / CrO₃, AcOH / 60 h / Ambient temperature

6: 15 percent / Jones' reagent / acetone / 6 h / Ambient temperature

7: 17 percent / Pb(OAc)4 / benzene; pyridine / 1.) room temperature, 1 h, 2.) reflux, 3 h

8: 6 mg / NaBH₄ / ethanol / 10 h

With chromium(VI) oxide; lead(IV) acetate; hydrogenchloride; sodium tetrahydroborate; jones' reagent; ethanol; hydrogen; iodine; sodium; acetic acid; calcium carbonate; palladium on activated charcoal; In pyridine; methanol; ethanol; cyclohexane; acetone; benzene;