bis(cyclopentadienyl)methylphenyltungsten hexafluorophosphate

Base Information

Chemical Name:bis(cyclopentadienyl)methylphenyltungsten hexafluorophosphate
CAS No.:89711-01-3
Molecular Formula:C₁₇H₁₈W*F₆P
Molecular Weight:551.144
Hs Code.:

Synonyms:bis(cyclopentadienyl)methylphenyltungsten hexafluorophosphate

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Chemical Property of bis(cyclopentadienyl)methylphenyltungsten hexafluorophosphate

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Technology Process of bis(cyclopentadienyl)methylphenyltungsten hexafluorophosphate

There total 5 articles about bis(cyclopentadienyl)methylphenyltungsten hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: ferrocenium hexafluorophosphate

: 89710-99-6
W(C₅H₅)2(CH₃)C₆H₅

: 102-54-5,55404-68-7
ferrocene

: 89711-01-3
bis(cyclopentadienyl)methylphenyltungsten hexafluorophosphate

Guidance literature:: In dichloromethane; 1 equiv of Cp2FePF6 added at -78°C as 0.014 M soln. in CH2Cl2 to-78°C soln. of WCp2(Me)Ph in CH2Cl2, stirred for 2 h at -78°C, warmed to -45°C; evapd., triturated with toluene, dried in vac., recrystd. from CH2Cl2; elem. anal.;
DOI:10.1021/ja00322a044

Reference yield: 82.0%

: 89710-99-6
W(C₅H₅)2(CH₃)C₆H₅

: 437-17-2
tritylium hexafluorophosphate

: 89711-01-3
bis(cyclopentadienyl)methylphenyltungsten hexafluorophosphate

Guidance literature:: In dichloromethane; a CH2Cl2 soln. of Ph3CPF6 was added at -78°C under inert atmosphere to a stirred soln. of Cp2WMePh in CH2Cl2, after 10 min soln. was warmed to -45°C; solvent was removed under reduced pressure over 3 h, residue was triturated with toluene at -45°C, dried in vacuo; identified spect. (IRand ESR);
DOI:10.1021/om00135a021

Reference yield: 43.0%

: ferrocenium hexafluorophosphate

: 89710-99-6
W(C₅H₅)2(CH₃)C₆H₅

: 89711-01-3
bis(cyclopentadienyl)methylphenyltungsten hexafluorophosphate

Guidance literature:: In dichloromethane; a CH2Cl2 soln. of Cp2FePF6 was added at -78°C to a CH2Cl2 soln. of Cp2WMePh under inert atmosphere, mixt. was stirred in the dark at -78°C for 2 h, warmed to -45°C; solvent was removed under reduced pressure (4 h), residue washed with toluene to give a spect. pure product (IR and ESR), anal. pure material was obtained by careful concn. over ca. 30 min of a CH2Cl2 soln. of the salt at room temp.; elem. anal.;
DOI:10.1021/om00135a021