(S)-Allyl-phosphonic acid phenyl ester (S)-1-trityloxymethyl-allyl ester

Base Information

Chemical Name:(S)-Allyl-phosphonic acid phenyl ester (S)-1-trityloxymethyl-allyl ester
CAS No.:375373-52-7
Molecular Formula:C₃₂H₃₁O₄P
Molecular Weight:510.569
Hs Code.:

Synonyms:(S)-Allyl-phosphonic acid phenyl ester (S)-1-trityloxymethyl-allyl ester

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Chemical Property of (S)-Allyl-phosphonic acid phenyl ester (S)-1-trityloxymethyl-allyl ester

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Technology Process of (S)-Allyl-phosphonic acid phenyl ester (S)-1-trityloxymethyl-allyl ester

There total 1 articles about (S)-Allyl-phosphonic acid phenyl ester (S)-1-trityloxymethyl-allyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

: 101111-39-1
diphenyl allylphosphonate

: Lithium; (S)-1-trityloxy-but-3-en-2-olate

: (R)-Allyl-phosphonic acid phenyl ester (S)-1-trityloxymethyl-allyl ester

: 375373-52-7
(S)-Allyl-phosphonic acid phenyl ester (S)-1-trityloxymethyl-allyl ester

Guidance literature:: In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; at -78 ℃;
DOI:10.1021/ol016491p

Reference yield:

: 375373-52-7
(S)-Allyl-phosphonic acid phenyl ester (S)-1-trityloxymethyl-allyl ester

: 375373-55-0
(2S,4R,5S,6R)-6-Hydroxymethyl-2-oxo-2-phenoxy-2λ⁵-[1,2]oxaphosphinane-4,5-diol

Guidance literature:: Multi-step reaction with 3 steps

1: 97.4 percent / (PCy₃)2Cl₂Ru=CHPh / CH₂Cl₂ / 5 h / Heating

2: 69.6 percent / aq. OsO₄; NMO; citric acid / acetone; 2-methyl-propan-2-ol / 24 h

3: 93.8 percent / TsOH / methanol / 24 h

With osmium(VIII) oxide; N-methyl-2-indolinone; toluene-4-sulfonic acid; citric acid; Grubbs catalyst first generation; In methanol; dichloromethane; acetone; tert-butyl alcohol;
DOI:10.1021/ol016491p

Reference yield:

: 375373-52-7
(S)-Allyl-phosphonic acid phenyl ester (S)-1-trityloxymethyl-allyl ester

: 375373-54-9
(2S,4R,5S,6R)-2-Oxo-2-phenoxy-6-trityloxymethyl-2λ⁵-[1,2]oxaphosphinane-4,5-diol

Guidance literature:: Multi-step reaction with 2 steps

1: 97.4 percent / (PCy₃)2Cl₂Ru=CHPh / CH₂Cl₂ / 5 h / Heating

2: 69.6 percent / aq. OsO₄; NMO; citric acid / acetone; 2-methyl-propan-2-ol / 24 h

With osmium(VIII) oxide; N-methyl-2-indolinone; citric acid; Grubbs catalyst first generation; In dichloromethane; acetone; tert-butyl alcohol;
DOI:10.1021/ol016491p