(3Z)-4-(benzoyloxy)-1-(α-furyl)-1-methoxy-3-<(trimethylsilyl)oxy>-1,3-butadiene

Base Information

Chemical Name:(3Z)-4-(benzoyloxy)-1-(α-furyl)-1-methoxy-3-<(trimethylsilyl)oxy>-1,3-butadiene
CAS No.:102650-39-5
Molecular Formula:C₁₉H₂₂O₅Si
Molecular Weight:358.466
Hs Code.:

Synonyms:(3Z)-4-(benzoyloxy)-1-(α-furyl)-1-methoxy-3-<(trimethylsilyl)oxy>-1,3-butadiene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (3Z)-4-(benzoyloxy)-1-(α-furyl)-1-methoxy-3-<(trimethylsilyl)oxy>-1,3-butadiene

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Technology Process of (3Z)-4-(benzoyloxy)-1-(α-furyl)-1-methoxy-3-<(trimethylsilyl)oxy>-1,3-butadiene

There total 3 articles about (3Z)-4-(benzoyloxy)-1-(α-furyl)-1-methoxy-3-<(trimethylsilyl)oxy>-1,3-butadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 27607-77-8
trimethylsilyl trifluoromethanesulfonate

: 4-(benzoyloxy)-1-(α-furyl)-1-methoxy-1-buten-3-one

: 102650-39-5
(3Z)-4-(benzoyloxy)-1-(α-furyl)-1-methoxy-3-<(trimethylsilyl)oxy>-1,3-butadiene

Guidance literature:: With triethylamine; In diethyl ether; 1.) -78 deg C, 10 min; 2.) room temp., 0.5 h;
DOI:10.1021/ja00291a030

Reference yield:

: 54150-57-1
2-benzoyloxyacetyl chloride

: 102650-39-5
(3Z)-4-(benzoyloxy)-1-(α-furyl)-1-methoxy-3-<(trimethylsilyl)oxy>-1,3-butadiene

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) hexamethyldisilazane, N-butyllithium; 2.) HCl (2N) / 1.) THF, 0 deg C, 1 h; 2.) toluene, -78 deg C, 35 min

2: 100 percent / diethyl ether / 0.67 h / 0 °C

3: 100 percent / triethylamine (Et₃N) / diethyl ether / 1.) -78 deg C, 10 min; 2.) room temp., 0.5 h

With hydrogenchloride; n-butyllithium; triethylamine; 1,1,1,3,3,3-hexamethyl-disilazane; In diethyl ether;
DOI:10.1021/ja00291a030

Reference yield:

: 92641-45-7
4-(benzoyloxy)-1-(α-furyl)-1,3-butanedione

: 102650-39-5
(3Z)-4-(benzoyloxy)-1-(α-furyl)-1-methoxy-3-<(trimethylsilyl)oxy>-1,3-butadiene

Guidance literature:: Multi-step reaction with 2 steps

1: 100 percent / diethyl ether / 0.67 h / 0 °C

2: 100 percent / triethylamine (Et₃N) / diethyl ether / 1.) -78 deg C, 10 min; 2.) room temp., 0.5 h

With triethylamine; In diethyl ether;
DOI:10.1021/ja00291a030