7-(tert-butyl-diphenyl-silanyloxy)-5-(4-methoxy-benzyloxy)-6-methyl-heptanal

Base Information

• Chemical Name: 7-(tert-butyl-diphenyl-silanyloxy)-5-(4-methoxy-benzyloxy)-6-methyl-heptanal
• CAS No.: 932699-72-4
• Molecular Formula: C₃₂H₄₂O₄Si
• Molecular Weight: 518.769
• Mol file: 932699-72-4.mol

Synonyms:7-(tert-butyl-diphenyl-silanyloxy)-5-(4-methoxy-benzyloxy)-6-methyl-heptanal

Chemical Property of 7-(tert-butyl-diphenyl-silanyloxy)-5-(4-methoxy-benzyloxy)-6-methyl-heptanal

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 7-(tert-butyl-diphenyl-silanyloxy)-5-(4-methoxy-benzyloxy)-6-methyl-heptanal

There total 3 articles about 7-(tert-butyl-diphenyl-silanyloxy)-5-(4-methoxy-benzyloxy)-6-methyl-heptanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

tert-butyl-[3-(4-methoxy-benzyloxy)-2-methyl-oct-7-enyloxy]-diphenyl-silane (932699-71-3) → 7-(tert-butyl-diphenyl-silanyloxy)-5-(4-methoxy-benzyloxy)-6-methyl-heptanal (932699-72-4)

Guidance literature:

With sodium periodate; osmium(VIII) oxide; water; In 1,4-dioxane; tert-butyl alcohol; at 20 ℃;

DOI:10.1021/ol063087n

Reference yield:

p-Anisaldehyde dimethyl acetal (2186-92-7) → 7-(tert-butyl-diphenyl-silanyloxy)-5-(4-methoxy-benzyloxy)-6-methyl-heptanal (932699-72-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 88 percent / OsO₄; H₂O; NaIO₄ / 2-methyl-propan-2-ol; dioxane / 20 °C

With sodium periodate; osmium(VIII) oxide; water; In 1,4-dioxane; tert-butyl alcohol; 2: Lemieux-Johnson oxidation;

DOI:10.1021/ol063087n

Reference yield:

tert-butylchlorodiphenylsilane (58479-61-1) → 7-(tert-butyl-diphenyl-silanyloxy)-5-(4-methoxy-benzyloxy)-6-methyl-heptanal (932699-72-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 88 percent / OsO₄; H₂O; NaIO₄ / 2-methyl-propan-2-ol; dioxane / 20 °C

With sodium periodate; osmium(VIII) oxide; water; In 1,4-dioxane; tert-butyl alcohol; 2: Lemieux-Johnson oxidation;

DOI:10.1021/ol063087n

upstream raw materials:

tert-butyl-[3-(4-methoxy-benzyloxy)-2-methyl-oct-7-enyloxy]-diphenyl-silane

p-Anisaldehyde dimethyl acetal

tert-butylchlorodiphenylsilane