ClF₆⁽¹⁺⁾*AsF₆^(1-)=(ClF₆)(AsF₆)

Base Information

• Chemical Name: ClF₆⁽¹⁺⁾*AsF₆^(1-)=(ClF₆)(AsF₆)
• CAS No.: 86527-33-5
• Molecular Formula: AsF₆*ClF₆
• Molecular Weight: 338.355
• Mol file: 86527-33-5.mol

Synonyms:ClF₆⁽¹⁺⁾*AsF₆^(1-)=(ClF₆)(AsF₆)

Chemical Property of ClF₆⁽¹⁺⁾*AsF₆^(1-)=(ClF₆)(AsF₆)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of ClF₆⁽¹⁺⁾*AsF₆^(1-)=(ClF₆)(AsF₆)

There total 1 articles about ClF₆⁽¹⁺⁾*AsF₆^(1-)=(ClF₆)(AsF₆) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

chlorine pentafluoride (478167-76-9,478167-78-1,184851-42-1,13637-63-3,676353-68-7) + 2Cs(1+)*NiF6(2-) = Cs2NiF6 + arsenic pentafluoride (7784-36-3) → ClF6(1+)*AsF6(1-)=(ClF6)(AsF6) (86527-33-5) + Ni(2+)*NiF6(2-)=NiNiF6 + Ni(2+)*2AsF6(1-)=Ni(AsF6)2 + ClF4(1+)*AsF6(1-)=ClF4AsF6 (41646-46-2) + cesium hexafluoroarsenate (18424-16-3)

Guidance literature:

In hydrogen fluoride; Cs2NiF6 was placed in trap, suspended at -60°C in ClF5, HF was condensed at -60°C, AsF5 was added, stirred at -60°C, 0.5 h at -60-40°C, 14 h at -60-10°C; volatiles removed in vac. at 25°C, suspended in HF at 25.degre.C,filtered under Ar, cooled to -196°C under vac., stirred with HF at 25°C, filtered at -78°C under Ar, washed with HF at -78 °C, dried in vac. for 12 h;

DOI:10.1021/ic001024+

Reference yield: 55.0%

caesium tetrafluoroborate (18909-69-8) + ClF6(1+)*AsF6(1-)=(ClF6)(AsF6) (86527-33-5) → chlorine pentafluoride (478167-76-9,478167-78-1,184851-42-1,13637-63-3,676353-68-7) + cesium hexafluoroarsenate (18424-16-3) + ClF6(1+)*BF4(1-)=ClF6BF4 (85662-38-0) + boron trifluoride (7637-07-2)

Guidance literature:

In hydrogen fluoride; dry HF condensed at -196°C onto mixt. of ClF6AsF6 and CsBF4, warmed for 30 min to 25°C with stirring; cooled to -78°C, filtered under N2 (2 atm), volatile at 25°C pumped off for 1.5 h, sepd. by fractional condensation through series of traps kept at -112, -142, and -196°C; IR, Raman anal.;

Reference yield:

ClF6(1+)*AsF6(1-)=(ClF6)(AsF6) (86527-33-5) → chlorine pentafluoride (478167-76-9,478167-78-1,184851-42-1,13637-63-3,676353-68-7) + arsenic pentafluoride (7784-36-3)

Guidance literature:

byproducts: F2; heating above 110°C; IR;

upstream raw materials:

chlorine pentafluoride

arsenic pentafluoride

Downstream raw materials:

chlorine pentafluoride

arsenic pentafluoride

cesium hexafluoroarsenate

ClF₆⁽¹⁺⁾*BF₄^(1-)=ClF₆BF₄