[(HC(C(CH3)N(2,6-iPr2C6H3)2)2)aluminum(μ-S)2titanium(C5H5)2]

Base Information

• Chemical Name: [(HC(C(CH3)N(2,6-iPr2C6H3)2)2)aluminum(μ-S)2titanium(C5H5)2]
• CAS No.: 831223-15-5
• Molecular Formula: C₃₉H₅₁AlN₂S₂Ti
• Molecular Weight: 686.841
• Mol file: 831223-15-5.mol

Synonyms:[(HC(C(CH3)N(2,6-iPr2C6H3)2)2)aluminum(μ-S)2titanium(C5H5)2]

Chemical Property of [(HC(C(CH3)N(2,6-iPr2C6H3)2)2)aluminum(μ-S)2titanium(C5H5)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(HC(C(CH3)N(2,6-iPr2C6H3)2)2)aluminum(μ-S)2titanium(C5H5)2]

There total 1 articles about [(HC(C(CH3)N(2,6-iPr2C6H3)2)2)aluminum(μ-S)2titanium(C5H5)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis(cyclopentadienyl)titanium dichloride (1271-19-8) + ((LiS)(HS)Al(HC(C(CH3)N(2,6-iPr2C6H3)2)(thf)2)2 (831223-14-4) → [HC(C(Me)N(2,6-(i)Pr2C6H3))2]Al(SH)2 (501081-97-6) + [(HC(C(CH3)N(2,6-iPr2C6H3)2)2)aluminum(μ-S)2titanium(C5H5)2] (831223-15-5) + ((HS)SAl(HC(C(CH3)N(2,6-iPr2C6H3)2))2Ti(C5H5)2 + lithium chloride

Guidance literature:

In tetrahydrofuran; reactiom at -20 °C;

DOI:10.1002/anie.200461254

Reference yield: 60.0%

[(HC(C(CH3)N(2,6-iPr2C6H3)2)2)aluminum(μ-S)2titanium(C5H5)2] (831223-15-5) + water (7732-18-5) → [(HC(C(CH3)N(2,6-iPr2C6H3)2)2)aluminum(OH)(μ-O)titanium(C5H5)2(SH)] (869493-72-1)

Guidance literature:

In tetrahydrofuran; dichloromethane; byproducts: H2S; under N2 or Ar; H2O added quickly to soln. of (HC(C(CH3)N(C6H3(CH(CH3)2)2))2)Al(S)2Ti(C5H5)2 in THF/CH2Cl2 (1/1) at room temp., suspn. stirred for 10 h; filtered, filtrate evapd. under vac., residue treated twice with cold toluene, filtered, dried under vac.; elem. anal.;

DOI:10.1002/anie.200501509

Reference yield:

[(HC(C(CH3)N(2,6-iPr2C6H3)2)2)aluminum(μ-S)2titanium(C5H5)2] (831223-15-5) + water (7732-18-5) → [(HC(C(CH3)N(2,6-iPr2C6H3)2)2)aluminum(SH)(μ-O)Ti(C5H5)2(SH)] (869493-75-4) + [(HC(C(CH3)N(2,6-iPr2C6H3)2)2)aluminum(OH)(μ-O)titanium(C5H5)2(SH)] (869493-72-1)

Guidance literature:

In tetrahydrofuran; byproducts: H2S; under N2 or Ar; H2O added quickly to soln. of (HC(C(CH3)N(C6H3(CH(CH3)2)2))2)Al(S)2Ti(C5H5)2 in THF at room temp., mixt. stirred overnight; ppt. filtered off, dried under vac.; mixt. obtained;

DOI:10.1002/anie.200501509

upstream raw materials:

bis(cyclopentadienyl)titanium dichloride

((LiS)(HS)Al(HC(C(CH₃)N(2,6-iPr₂C₆H₃)2)(thf)2)2

Downstream raw materials:

[(HC(C(CH3)N(2,6-iPr2C6H3)2)2)aluminum(SH)(μ-O)Ti(C5H5)2(SH)]

[(HC(C(CH3)N(2,6-iPr2C6H3)2)2)aluminum(OH)(μ-O)titanium(C5H5)2(SH)]