C₅₀H₈₇IO₁₁SSi₂

Base Information

Chemical Name:C₅₀H₈₇IO₁₁SSi₂
CAS No.:1316278-94-0
Molecular Formula:C₅₀H₈₇IO₁₁SSi₂
Molecular Weight:1079.38
Hs Code.:

C<sub>50</sub>H<sub>87</sub>IO<sub>11</sub>SSi<sub>2</sub>

Synonyms:C₅₀H₈₇IO₁₁SSi₂

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of C₅₀H₈₇IO₁₁SSi₂

Chemical Property:

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Technology Process of C₅₀H₈₇IO₁₁SSi₂

There total 23 articles about C₅₀H₈₇IO₁₁SSi₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 871348-24-2
2-((2S,3S,4R,5R)-5-((S)-2,3-bis((tert-butyldimethylsilyl)oxy)propyl)-4-methoxy-3-((phenylsulfonyl)methyl)tetrahydrofuran-2-yl)acetaldehyde

: 1316278-93-9
3-((2S,3aS,5R,7aS)-3a-(iodomethyl)-5-((R)-2-methyl-3-(((trifluoromethyl)sulfonyl)oxy)but-3-en-1-yl)hexahydro-2H-furo[3,2-b]pyran-2-yl)propyl pivalate

: 1316278-94-0
C₅₀H₈₇IO₁₁SSi₂

Guidance literature:: 2-((2S,3S,4R,5R)-5-((S)-2,3-bis((tert-butyldimethylsilyl)oxy)propyl)-4-methoxy-3-((phenylsulfonyl)methyl)tetrahydrofuran-2-yl)acetaldehyde; 3-((2S,3aS,5R,7aS)-3a-(iodomethyl)-5-((R)-2-methyl-3-(((trifluoromethyl)sulfonyl)oxy)but-3-en-1-yl)hexahydro-2H-furo[3,2-b]pyran-2-yl)propyl pivalate; With chromium dichloride; triethylamine; nickel dichloride; (S)-N-(2-(4-isopropyl-4,5-dihydrooxazol-2-yl)-6-methylphenyl)methane sulfonamide; In tetrahydrofuran; at 22 - 24 ℃; for 20.5h; Inert atmosphere;

With ethylenediamine; In tetrahydrofuran; n-heptane; water; at 0 - 5 ℃; for 1h;

Reference yield:

: 1316279-31-8
C₅₀H₈₅IO₁₁SSi₂

: 1316278-94-0
C₅₀H₈₇IO₁₁SSi₂

: C₅₀H₈₇IO₁₁SSi₂

Guidance literature:: C₅₀H₈₅IO₁₁SSi₂; With lithium borohydride; In tetrahydrofuran; toluene; at 0 ℃; for 0.333333h;

With citric acid; In tetrahydrofuran; tert-butyl methyl ether; water; toluene;

Reference yield:

: 1139773-78-6
C₁₆H₂₅NO₅

: 1316278-94-0
C₅₀H₈₇IO₁₁SSi₂

Guidance literature:: Multi-step reaction with 12 steps

1.1: 1H-imidazole / N,N-dimethyl-formamide / 2 h / 0 - 20 °C

2.1: lithium borohydride / tetrahydrofuran / 16 h / 0 - 23 °C

2.2: 0.5 h / 0 - 10 °C

3.1: dmap; triethylamine / dichloromethane / 2 h / 0 - 22 °C

4.1: zinc / methanesulfonic acid / tetrahydrofuran / 5 h / Reflux

5.1: water; acetic acid / tetrahydrofuran / 10 h / 10 - 20 °C

6.1: hydrogen / palladium 10% on activated carbon / ethyl acetate / 2 h / 20 °C

7.1: toluene / 0.25 h / 95 °C

8.1: potassium hexamethylsilazane / toluene; tetrahydrofuran / 1 h / -30 - -25 °C

9.1: hydrogenchloride / isopropyl alcohol; methanol / 1 h / 20 °C

10.1: pyridine / dichloromethane / 1 h / -10 - 0 °C

11.1: sodium iodide / dichloromethane; N,N-dimethyl-formamide / 3 h / 20 - 22 °C

12.1: triethylamine; nickel dichloride; chromium dichloride; (S)-N-(2-(4-isopropyl-4,5-dihydrooxazol-2-yl)-6-methylphenyl)methane sulfonamide / tetrahydrofuran / 20.5 h / 22 - 24 °C / Inert atmosphere

12.2: 1 h / 0 - 5 °C

With pyridine; 1H-imidazole; chromium dichloride; hydrogenchloride; dmap; lithium borohydride; water; hydrogen; potassium hexamethylsilazane; acetic acid; triethylamine; sodium iodide; nickel dichloride; zinc; (S)-N-(2-(4-isopropyl-4,5-dihydrooxazol-2-yl)-6-methylphenyl)methane sulfonamide; methanesulfonic acid; palladium 10% on activated carbon; In tetrahydrofuran; methanol; dichloromethane; ethyl acetate; N,N-dimethyl-formamide; isopropyl alcohol; toluene; 12.1: Nozaki-Hiyama-Kishi Coupling;