zinc (II) (5,15-bis[3,4,5-tri(hexadecyloxy)phenyl]-10,20-bis(ethynyl)porphyrinate)

Base Information

• Chemical Name: zinc (II) (5,15-bis[3,4,5-tri(hexadecyloxy)phenyl]-10,20-bis(ethynyl)porphyrinate)
• CAS No.: 908118-36-5
• Molecular Formula: C₁₃₂H₂₁₂N₄O₆Zn
• Molecular Weight: 2016.55
• Mol file: 908118-36-5.mol

Synonyms:zinc (II) (5,15-bis[3,4,5-tri(hexadecyloxy)phenyl]-10,20-bis(ethynyl)porphyrinate)

Chemical Property of zinc (II) (5,15-bis[3,4,5-tri(hexadecyloxy)phenyl]-10,20-bis(ethynyl)porphyrinate)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of zinc (II) (5,15-bis[3,4,5-tri(hexadecyloxy)phenyl]-10,20-bis(ethynyl)porphyrinate)

There total 1 articles about zinc (II) (5,15-bis[3,4,5-tri(hexadecyloxy)phenyl]-10,20-bis(ethynyl)porphyrinate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C138H228N4O6Si2Zn → zinc (II) (5,15-bis[3,4,5-tri(hexadecyloxy)phenyl]-10,20-bis(ethynyl)porphyrinate) (908118-36-5)

Guidance literature:

With tetrabutyl ammonium fluoride; In tetrahydrofuran; for 2h; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.macromol.5b01607

Reference yield: 62.0%

trans-dichloro-bis(tri-n-butylphosphine)platinum(II) (15391-01-2,15076-72-9,15390-92-8) + zinc (II) (5,15-bis[3,4,5-tri(hexadecyloxy)phenyl]-10,20-bis(ethynyl)porphyrinate) (908118-36-5) → Zn(II)[5,15-bis(3,4,5-tri(hexadecyloxy)phenyl)-10-ethynyl-20-(2-trans-bis(tri-n-butylphosphine)platinum(II)-ethynyl]porphyrin]

Guidance literature:

With CuI; In dichloromethane; (under Ar, Schlenk); Zn-complex reacted with Pt-complex in iPr2NH-CH2Cl21:1 in presence of CuI for 12 h at 65°C; diluted by CH2Cl2, washed with H2O, organic layer collected, volatiles removed under reduced pressure, washed with CH2Cl2;

DOI:10.1021/ic901421m

Reference yield: 54.0%

zinc (II) (5,15-bis[3,4,5-tri(hexadecyloxy)phenyl]-10,20-bis(ethynyl)porphyrinate) (908118-36-5) + C17H12INO2 → C166H234N6O10Zn

Guidance literature:

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; triphenyl-arsane; triethylamine; In tetrahydrofuran; at 45 ℃; for 48h; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.macromol.5b01607

Downstream raw materials:

Zn[5,15-bis[3,4,5-tri(hexadecyloxy)phenyl]-10,20-bis(2-(ethynylbenzene)bis(tri-n-butylphosphine)platinum(II)ethynyl)porphyrin]