3-deoxy-1,2:5,6-di-O-isopropylidene-3-(4-[2-fluoroethoxy]benzamidyl)-α-D-allofuranose

Base Information

Chemical Name:3-deoxy-1,2:5,6-di-O-isopropylidene-3-(4-[2-fluoroethoxy]benzamidyl)-α-D-allofuranose
CAS No.:1312717-13-7
Molecular Formula:C₂₁H₂₈FNO₇
Molecular Weight:425.454
Hs Code.:

Synonyms:3-deoxy-1,2:5,6-di-O-isopropylidene-3-(4-[2-fluoroethoxy]benzamidyl)-α-D-allofuranose

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 3-deoxy-1,2:5,6-di-O-isopropylidene-3-(4-[2-fluoroethoxy]benzamidyl)-α-D-allofuranose

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of 3-deoxy-1,2:5,6-di-O-isopropylidene-3-(4-[2-fluoroethoxy]benzamidyl)-α-D-allofuranose

There total 3 articles about 3-deoxy-1,2:5,6-di-O-isopropylidene-3-(4-[2-fluoroethoxy]benzamidyl)-α-D-allofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 21870-78-0
3-azido-3-deoxy-1,2:5,6-di-O-isopropylidene-α-D-allofuranose

: 1200959-88-1
2-(diphenylphosphano)phenyl 4-(2-fluoroethoxy)-benzoate

: 1312717-13-7
3-deoxy-1,2:5,6-di-O-isopropylidene-3-(4-[2-fluoroethoxy]benzamidyl)-α-D-allofuranose

Guidance literature:: In water; N,N-dimethyl-formamide; at 60 ℃; for 2h;
DOI:10.1016/j.tet.2011.04.091

Reference yield:

: 1200959-80-3
2-iodophenyl 4-(2-hydroxyethoxy)benzoate

: 1312717-13-7
3-deoxy-1,2:5,6-di-O-isopropylidene-3-(4-[2-fluoroethoxy]benzamidyl)-α-D-allofuranose

Guidance literature:: Multi-step reaction with 3 steps

1: diethylamino-sulfur trifluoride / dichloromethane / -78 - 20 °C / Inert atmosphere

2: potassium acetate; palladium diacetate / 2,4-dichlorophenoxyacetic acid dimethylamine / 70 °C / Inert atmosphere

3: water; N,N-dimethyl-formamide / 2 h / 60 °C

With diethylamino-sulfur trifluoride; potassium acetate; palladium diacetate; In dichloromethane; water; 2,4-dichlorophenoxyacetic acid dimethylamine; N,N-dimethyl-formamide;
DOI:10.1016/j.tet.2011.04.091

Reference yield:

: 1200959-82-5
2-iodophenyl 4-(2-fluoroethoxy)benzoate

: 1312717-13-7
3-deoxy-1,2:5,6-di-O-isopropylidene-3-(4-[2-fluoroethoxy]benzamidyl)-α-D-allofuranose

Guidance literature:: Multi-step reaction with 2 steps

1: potassium acetate; palladium diacetate / 2,4-dichlorophenoxyacetic acid dimethylamine / 70 °C / Inert atmosphere

2: water; N,N-dimethyl-formamide / 2 h / 60 °C

With potassium acetate; palladium diacetate; In water; 2,4-dichlorophenoxyacetic acid dimethylamine; N,N-dimethyl-formamide;
DOI:10.1016/j.tet.2011.04.091