tert-Butyl 3-(2-methoxycarbonylethyl)-4-methoxycarbonylmethyl-5-(phenylsulfinylmethyl)pyrrole-2-carboxylate

Base Information

Chemical Name:tert-Butyl 3-(2-methoxycarbonylethyl)-4-methoxycarbonylmethyl-5-(phenylsulfinylmethyl)pyrrole-2-carboxylate
CAS No.:145045-63-2
Molecular Formula:C₂₃H₂₉NO₇S
Molecular Weight:463.552
Hs Code.:

Synonyms:tert-Butyl 3-(2-methoxycarbonylethyl)-4-methoxycarbonylmethyl-5-(phenylsulfinylmethyl)pyrrole-2-carboxylate

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Chemical Property of tert-Butyl 3-(2-methoxycarbonylethyl)-4-methoxycarbonylmethyl-5-(phenylsulfinylmethyl)pyrrole-2-carboxylate

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Technology Process of tert-Butyl 3-(2-methoxycarbonylethyl)-4-methoxycarbonylmethyl-5-(phenylsulfinylmethyl)pyrrole-2-carboxylate

There total 6 articles about tert-Butyl 3-(2-methoxycarbonylethyl)-4-methoxycarbonylmethyl-5-(phenylsulfinylmethyl)pyrrole-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 145045-62-1
tert-Butyl 3-(2-methoxycarbonylethyl)-4-methoxycarbonylmethyl-5-(phenylthiomethyl)pyrrole-2-carboxylate

: 145045-63-2
tert-Butyl 3-(2-methoxycarbonylethyl)-4-methoxycarbonylmethyl-5-(phenylsulfinylmethyl)pyrrole-2-carboxylate

Guidance literature:: With sodium periodate; In methanol; water; at 40 ℃; for 20h;
DOI:10.1039/P19920002175

Reference yield:

: 66697-04-9
1-tert-butyl, 6-methyl 3-oxo-1,6-hexanedicarboxylate

: 145045-63-2
tert-Butyl 3-(2-methoxycarbonylethyl)-4-methoxycarbonylmethyl-5-(phenylsulfinylmethyl)pyrrole-2-carboxylate

Guidance literature:: Multi-step reaction with 5 steps

1: 1) AcOH, NaNO₂, 2) AcOH, Zn, NaOAc / 1) water, 16 h, 2) 60-65 deg C, 1 h

2: 73 percent / Tl(NO₃)3, conc. HNO₃ / 6 h

3: SO₂Cl₂, K₂CO₃ / CH₂Cl₂ / 1) 10 min, 0 deg C, 2) 10 min, 20 deg C

4: CH₂Cl₂ / 2 h / 20 °C

5: 95 percent / NaIO₄ / methanol; H₂O / 20 h / 40 °C

With sodium periodate; sulfuryl dichloride; nitric acid; sodium acetate; potassium carbonate; acetic acid; thallium(III) nitrate; zinc; sodium nitrite; In methanol; dichloromethane; water;
DOI:10.1039/P19920002175

Reference yield:

: 101210-29-1
5-Chloromethyl-3-(2-methoxycarbonyl-ethyl)-4-methoxycarbonylmethyl-1H-pyrrole-2-carboxylic acid tert-butyl ester

: 145045-63-2
tert-Butyl 3-(2-methoxycarbonylethyl)-4-methoxycarbonylmethyl-5-(phenylsulfinylmethyl)pyrrole-2-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: CH₂Cl₂ / 2 h / 20 °C

2: 95 percent / NaIO₄ / methanol; H₂O / 20 h / 40 °C

With sodium periodate; In methanol; dichloromethane; water;
DOI:10.1039/P19920002175