2-{(E)-2-[Dimethyl-(4-methyl-pentyloxy)-silanyl]-vinyl}-phenol

Base Information

• Chemical Name: 2-{(E)-2-[Dimethyl-(4-methyl-pentyloxy)-silanyl]-vinyl}-phenol
• CAS No.: 152753-76-9
• Molecular Formula: C₁₆H₂₆O₂Si
• Molecular Weight: 278.467
• Mol file: 152753-76-9.mol

Synonyms:2-{(E)-2-[Dimethyl-(4-methyl-pentyloxy)-silanyl]-vinyl}-phenol

Chemical Property of 2-{(E)-2-[Dimethyl-(4-methyl-pentyloxy)-silanyl]-vinyl}-phenol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-{(E)-2-[Dimethyl-(4-methyl-pentyloxy)-silanyl]-vinyl}-phenol

There total 3 articles about 2-{(E)-2-[Dimethyl-(4-methyl-pentyloxy)-silanyl]-vinyl}-phenol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

4-Methyl-1-pentanol (626-89-1) + Acetic acid 2-[(E)-2-(chloro-dimethyl-silanyl)-vinyl]-phenyl ester → 2-{(E)-2-[Dimethyl-(4-methyl-pentyloxy)-silanyl]-vinyl}-phenol (152753-76-9)

Guidance literature:

Acetic acid 2-[(E)-2-(chloro-dimethyl-silanyl)-vinyl]-phenyl ester; With lithium dimethylamide; In tetrahydrofuran;

4-Methyl-1-pentanol; In tetrahydrofuran; at 20 ℃; for 3h; Further stages.;

DOI:10.1021/ja002370t

Reference yield: 95.0%

4-Methyl-1-pentanol (626-89-1) + 2-[(E)-2-(Dimethylamino-dimethyl-silanyl)-vinyl]-phenol → 2-{(E)-2-[Dimethyl-(4-methyl-pentyloxy)-silanyl]-vinyl}-phenol (152753-76-9)

Guidance literature:

In tetrahydrofuran; for 3h; Ambient temperature;

DOI:10.1021/jo00077a010

Reference yield:

2-acetoxyphenylacetylene → 2-{(E)-2-[Dimethyl-(4-methyl-pentyloxy)-silanyl]-vinyl}-phenol (152753-76-9)

Guidance literature:

Multi-step reaction with 2 steps

1.1: H₂PtCl₆

2.1: LiNMe₂ / tetrahydrofuran

2.2: 95 percent / tetrahydrofuran / 3 h / 20 °C

With dihydrogen hexachloroplatinate; lithium dimethylamide; In tetrahydrofuran;

DOI:10.1021/ja002370t

upstream raw materials:

4-Methyl-1-pentanol

Downstream raw materials:

4-Methyl-1-pentanol