[Ti(pentamethylcyclopentadienyl)(N(xylyl)C₄H₆N)(diphenylhydrazinediido)(tert-butylamine)]

Base Information

• Chemical Name: [Ti(pentamethylcyclopentadienyl)(N(xylyl)C₄H₆N)(diphenylhydrazinediido)(tert-butylamine)]
• CAS No.: 1160299-00-2
• Molecular Formula: C₃₈H₅₁N₅Ti
• Molecular Weight: 625.736
• Mol file: 1160299-00-2.mol

Synonyms:[Ti(pentamethylcyclopentadienyl)(N(xylyl)C₄H₆N)(diphenylhydrazinediido)(tert-butylamine)]

Chemical Property of [Ti(pentamethylcyclopentadienyl)(N(xylyl)C₄H₆N)(diphenylhydrazinediido)(tert-butylamine)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ti(pentamethylcyclopentadienyl)(N(xylyl)C₄H₆N)(diphenylhydrazinediido)(tert-butylamine)]

There total 1 articles about [Ti(pentamethylcyclopentadienyl)(N(xylyl)C₄H₆N)(diphenylhydrazinediido)(tert-butylamine)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

[Ti(pentamethylcyclopentadienyl)(N(xylyl)C4H6N)(tert-butylimido)(tert-butylamine)] (1160299-05-7) + 1,1-Diphenylhydrazine (530-50-7) → [Ti(pentamethylcyclopentadienyl)(N(xylyl)C4H6N)(diphenylhydrazinediido)(tert-butylamine)] (1160299-00-2)

Guidance literature:

In hexane; (Ar); using Schlenk techniques; addn. of H2NNPh2 (1 equiv.) to soln. of (C5Me5)Ti(N(xylyl)C4H6N)(N(t-Bu))(NH2(t-Bu)) (1 equiv.) in hexane; stirring at room temp. for 30 min; pptn., filtration, drying under reduced pressure, elem. anal.;

DOI:10.1021/om900155t

Reference yield: 60.0%

1-phenylpropadiene (2327-99-3) + [Ti(pentamethylcyclopentadienyl)(N(xylyl)C4H6N)(diphenylhydrazinediido)(tert-butylamine)] (1160299-00-2) → [Ti(η5-pentamethylcyclopentadienyl)((Xyl)-2-aminopyrrolinato)(κ2-N(NPh2)C(CHPh)CH2)] (1182849-23-5,1182199-37-6)

Guidance literature:

In toluene; (Ar); using Schlenk techniques; addn. of soln. phenylallene (1 equiv.) in toluene to soln. of (C5Me5)Ti(NH2(t-Bu))(N(Xyl)NC4H6)(NNPh2) in toluene, stirring at room temp. for 1 h; removal of all volatiles in vac., dissolving in pentane, crystn. at -18°C as mixt. of 2 isomers; elem. anal.;

DOI:10.1021/om900428d

Reference yield: 49.0%

[Ti(pentamethylcyclopentadienyl)(N(xylyl)C4H6N)(diphenylhydrazinediido)(tert-butylamine)] (1160299-00-2) → [Ti(pentamethylcyclopentadienyl)(N(xylyl)C4H6N)(diphenylhydrazinediido)] (1160299-07-9)

Guidance literature:

With B(C₆F₅)3; In hexane; (Ar); using Schlenk techniques; addn. of B(C6F5)3 (1 equiv.) to soln. of(C5Me5)Ti(N(xylyl)C4H6N)(NNPh2))(NH2(t-Bu)) (1 equiv.) in hexane; pptn. , stirring at room temp. for 1 h; filtration, removal of volatiles in vac., trituration in pentane; filtration, evapn. of extract to dryness; elem. anal.;

DOI:10.1021/om900155t

upstream raw materials:

[Ti(pentamethylcyclopentadienyl)(N(xylyl)C₄H₆N)(tert-butylimido)(tert-butylamine)]

1,1-Diphenylhydrazine

Downstream raw materials:

[Ti(pentamethylcyclopentadienyl)(N(xylyl)C₄H₆N)(diphenylhydrazinediido)]

[Ti(η5-pentamethylcyclopentadienyl)((Xyl)-2-aminopyrrolinato)(κ2-N(NPh2)C(CHPh)CH2)]

[Ti(η5-pentamethylcyclopentadienyl)((Xyl)-2-aminopyrrolinato)(κ2-N(NPh2)C(S)N(Ph))]

[Ti(η5-pentamethylcyclopentadienyl)((Xyl)-2-aminopyrrolinato)(κ2-N(NPh2)CN(Ph)S)]